The formation of benzoxacin-3-ones via intramolecular Nicholas reactions and synthesis of 8-membered heliannuols.
Org Biomol Chem
; 19(33): 7152-7155, 2021 09 07.
Article
em En
| MEDLINE
| ID: mdl-34373880
ABSTRACT
The γ-carbonyl cations generated from propargyl ether-Co2(CO)6 complexes undergo intramolecular Nicholas reactions to give dehydrobenzoxacin-3-one-Co2(CO)6 complexes in good yields. Reductive decomplexation and subsequent manipulation allows the synthesis of (±)-heliannuol K methyl ether and the formal syntheses of (±)-heliannuol K, (±)-heliannuol A, and (-)-heliannuol L.
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MEDLINE
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En
Ano de publicação:
2021
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Article