Combining hydrochemistry and hydrogen and oxygen stable isotopes to reveal the influence of human activities on surface water quality in Chaohu Lake Basin.

The input of pollutants caused by human activities induces the deterioration of surface water quality. To reveal the characteristics of surface water quality in Chaohu Lake Basin and the influence of human activities, the hydrochemistry and stable isotope composition of hydrogen and oxygen in lake water and inflow river water were analyzed. The results show that the hydrochemical type of lake water is the Na-Cl type,while river water is the Na-Cl, Ca-Cl and mixed types. The ion proportional coefficient method and principal component analysis show that surface water is controlled by weathering of evaporated salt rocks and silicate rocks, in which Cl- and SO42- are affected by fertilizers and sewage to some extent. There is a strong correlation between conventional ions and nutrient indexes, which indicates that dissolved ions are affected not only by rock weathering but also by human activities (such as the discharge of domestic sewage or nitrogen-containing wastewater and the use of fertilizers). The stable isotope values of hydrogen and oxygen in surface water are distributed at the lower right portion of the local precipitation line and are close to it, indicating that surface water mainly originates from precipitation. The high value of d-excess values in surface water indicates that evaporation is weak. As pollution indicators, EC, Cl- and NO3- indicates that the Nanfei River, Dianbu River, Shiwuli River and Pai River flow in northwestern of Chaohu Lake Basin through Hefei urban city are severely polluted, NO3- originates from manure and sewage. Rivers flowing through farmland areas are less polluted, and the use of agricultural fertilizer contributes greatly to NO3-.