Making Pb Adsorption-Saturated Attapulgite with Excellent Photocatalysis Properties through a Vulcanization Reaction and Its Application for MB Wastewater Degradation.
Int J Environ Res Public Health
; 19(16)2022 08 22.
Article
em En
| MEDLINE
| ID: mdl-36012092
ABSTRACT
Attapulgite (AT) is a clay mineral with rich reserves in China, and it has good adsorption activity for Pb-containing wastewater. However, as a hazardous waste, the treatment of Pb adsorption-saturated attapulgite was quite difficult. In this work, through a simple vulcanization reaction, the waste Pb adsorption-saturated attapulgite (AT@Pb) was transformed into composite materials (AT@PbS) with good photocatalytic performance. After comprehensive material characterization (including XRD, TEM, XPS, and UV-Vis), the photocatalytic degradation performance and mechanism of AT@PbS for methylene blue (MB) were investigated. The results revealed that AT@PbS was a composite material of attapulgite nanorods (500-600 nm) and nanosquare PbS particles (80-100 nm). Additionally, AT@PbS displayed good visible light absorption, improved photo-electric properties, excellent photodegradation performance for MB, and recycling stability. Moreover, the energy band range of AT@PbS was about -0.043 V to 1.367 V. The photo-generated holes and their derived hydroxyl radicals were the main active species for MB degradation. This work not only provides a new approach to construct the composite photocatalyst, but also demonstrates the possibility of the comprehensive utilization of heavy metal adsorbents for wastewater degradation.
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MEDLINE
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Águas Residuárias
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Azul de Metileno
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En
Ano de publicação:
2022
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Article