Dimeric Manganese-Catalyzed Direct Nucleophilic Addition of C(sp2)-H Bonds to Inert Aldehydes.
J Org Chem
; 87(21): 14487-14495, 2022 Nov 04.
Article
em En
| MEDLINE
| ID: mdl-36251701
ABSTRACT
An efficient direct nucleophilic addition reaction of C(sp2)-H bonds to aldehydes catalyzed by a dimeric manganese has been developed. This reaction has a broad range of substrates, and high yields were also obtained with inert aliphatic aldehydes as substrates. A dimeric Mn2(CO)8Br2 was proven to be a more efficient catalyst precursor than the monomeric Mn(CO)5Br.
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Base de dados:
MEDLINE
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En
Ano de publicação:
2022
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Article