Modeling Cu removal from aqueous solution using sawdust based on response surface methodology.

ABSTRACT

Copper (Cu), as one of the heavy metals widely used in industrial and agricultural activities, has a fundamental role in the pollution of water resources. Therefore, removing Cu from the aqueous solutions is considered an important challenge in the purification of water resources. Thus, in this study, sawdust with a diameter of 260-600 µm was used to remove Cu from the aqueous solutions. At first, sawdust was washed using distilled water and dried at laboratory temperature. Cu absorption experiments in closed conditions were performed based on the central composite design (CCD) model and with a range of initial Cu concentrations equal to 1-25 mgl-1. The amount of changes for other variables, including pH, time, and amount of sawdust, was equal to 2-10, 5-185 (min), and 5-25 (gl-1), respectively. After the completion of each test, the remaining Cu concentration in the solution was measured using atomic absorption, and the percentage of Cu removed was determined from the difference between the initial and final concentrations. The results showed that the CCD model has a favorable ability to predict Cu removal from the aqueous solutions (R2=0.90 and RSME=3.34%). Based on the Pareto analysis, contact time, the amount of sawdust, pH, and the Cu concentration had the most significant effect on removing Cu from the solution. Contact time, amount of sawdust, and pH were directly related, and the amount of dissolved Cu was proportional to the removal of Cu from the solution. Therefore, sawdust is desirable as a natural adsorbent, and the removal efficiency of Cu from solutions with low Cu concentration is very high (94%). In this regard, it is advised to use sawdust in the process of targeting Cu and heavy metals due to its low cost and availability.