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Enhanced d-π overlap in a graphene supported Ni/PtNi heterojunction for efficient seawater hydrogen evolution.
Yang, Xiong; Xiao, Yu-Xuan; Zhang, Xue-Qi; Yu, Fei; Tian, Ge; Zhao, Wen-Ying; Shen, Ling; Zhang, Song; Yang, Xiao-Yu.
Afiliação
  • Yang X; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
  • Xiao YX; School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, China.
  • Zhang XQ; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
  • Yu F; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
  • Tian G; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
  • Zhao WY; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
  • Shen L; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
  • Zhang S; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
  • Yang XY; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & Shenzhen Research Institute, Wuhan University of Technology, Wuhan, 430070, China. tiange@whut.edu.cn.
Chem Commun (Camb) ; 60(16): 2176-2179, 2024 Feb 20.
Article em En | MEDLINE | ID: mdl-38289337
ABSTRACT
d-π overlap, which represents overlap between metal-d and graphene-π orbitals to facilitate electron transfer, has rarely been reported. Ni/PtNi-G2 exhibits exceptional performance in seawater hydrogen evolution due to the electron-rich surface on Pt resulting from enhanced d-π overlap and subsequent electron transfer from graphene and Ni to Pt.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article