Tailor-designed carbon-based novel fluorescent architecture for nanomolar detection of radioactive elements U(VI) and Th(IV) in pH ± 5.0.

ABSTRACT

Highly stable nitrogen-doped Graphene Quantum Dots (N-GQD) functionalized with Pamoic Acid (PA@N-GQD) are utilized for nanomolar detection of radioactive elements, Uranium (VI) and Thorium (IV), in pH ± 5.0. The absorption, fluorescence, crystalline nature, elemental composition, functional groups, and morphological state of as-prepared PA@N-GQD are evaluated by UV-visible absorption, photoluminescence, XRD, XPS, FTIR, HRTEM, FESEM, and AFM characterizations. The aqueous solution of PA@N-GQD is characterized by its spherical morphology, averaging 6.5 nm in size. PA@N-GQD exhibits a gradual decrease in fluorescence intensity at 438 nm (λex 344 nm) upon the addition of Uranium (VI) and Thorium (IV) ions. The selectivity, sensitivity, competitivity, pH, time effect, and reversibility studies of PA@N-GQDs have been carried out using the photoluminescence technique. The attained fluorescence Limit of Detection (LoD) of PA@N-GQD for Uranium (VI) and Thorium (IV) ions are 2.009 × 10-9 and 1.351 × 10-9 M, respectively. From the fluorescence titration studies of U(VI) and Th(IV), the binding constant, Stern-Volmer constant, Modified Stern-Volmer constant, association constant, and dissociation constants have been calculated separately. These aforementioned results indicate that the PA@N-GQD has a higher binding affinity towards Th(IV) than U(VI) in aqueous medium. This current research represents the development of advanced materials for environmental and analytical applications, specifically focusing on the precise detection and quantification of radioactive elements.