摘要
Objective: To study the chemical constituents of Salacia cochinchinensis. Methods: The isolates were obtained by silica gel, Sephadex LH-20, MCI column chromatography, as well as prep-HPLC methods. Their structures were indentified on the basis of NMR, MS analyses. Results: Eight compounds were isolated from 90% ethanol extract of S. cochinchinensis. The structures were identified as 28-hydroxyl salaspermic acid (1), pachysandiol A (2), pristimeronol (3), 28-hydroxy-friedelan-3-one-29-oic acid (4), kaempferol-3-O-α-L-rhamnoside (5), 6,7-dimethoxy-4-hydroxyl-1-naphthoic acid (6), grasshopper ketone (7), 3,4,5-trimethoxyl benzoic acid methyl ester (8). Conclusion: Compound 1 is a new friedelane-type triterpenoid. Compounds 2-8 were isolated from the Salacia genus for the first time.
摘要
Objective To study the chemical constituents from the leaf of Syringa oblata. Methods The compounds was isolated by silica gel column chromatography and HPLC, and their structure were identified by spectral data analysis. Results A total of 35 compounds were isolated and identified as oleanolic acid (1), ursolic acid (2), betulinic acid (3), 1,3-benzodioxole-5-propanol (4), p-hydroxyl benzene propyl alcohol (5), p-hydroxyl benzene ethel alcohol (6), syringopicrogenin D (7), syringopicrogenin E (8), syringopicrogenin F (9), syringopicrogenin A (10), syringopicrogenin C (11), 3,4-dihydroxyl benzene ethel alcohol (12), syringobittergenin B (13), syringo-picrogenin B (14), grasshopper ketone (15), (7R,8S)-4,9,9’-trihydroxyl-3,3’-dimethoxyl-7,8- dihydrobenzofuran-1’-propylneolignan (16), lariciresinol (17), syringin (18), 3(Z)-enol glucoside (19), quercetin-3-O-β-D- glucopyranoside (20), (8E)-ligstroside (21), epipinoresinol-4-O-β-D-glucopyranoside (22), (8E)-ligstroside B (23), (8E)-ligstroside A (24), salidroside (25), 7-dehydrologanin (26), fliederoside B (27), syringopicroside B (28), oleoside dimethyl ester (29), lilacoside (30), syrigopicroside (31), oleuropein (32), (+)-lariciresinol-4-O-β-D-glucopyranoside (33), verbascoside (34), and (+)- epipinoresinol-4’-O-β-D-glucopyranoside (35). Conclusion Compounds 4, 5, 14-16, 19, 23, 24, 26, and 27 are isolated from S. oblata for the first time.
摘要
Objective: To investigate the chemical constituents of Adisia faberi. Methods: Compounds were isolated and purified by the normal phase silica gel, Sephadex LH-20, MCI gel, and ODS-A-HG packing material. Their structures were identified by the methods of MS, 1H-NMR, and 13C-NMR combined with physicochemical property. Results: Eleven compounds were isolated and their structures were elucidateasbauerenol (1), oleic acid (2), (Z)-10-heneicosenoic acid (3), grasshopper ketone (4), bergenin (5), mallonanoside A (6), ethyl gallate (7), astilbin (8), quercitrin (9), ardisiacrispin B (10), and ardicrenin (11). Conclusion: Compounds 2, 7, 9-11 are isolated from this plant for the first time; Compounds 3, 4, 6, and 8 are isolated from plants in genus Ardisia Swartz for the first time.
摘要
Objective: To study the chemical constituents in the leaves of Magnolia officinalis var. biloba. Methods: Compounds were isolated by various chromatographic techniques and identified by spectral analyses. Results: Twelve compounds were isolated in the 75% ethanol extract from the leaves of M. officinalis var. biloba and identified as lirioresinol-A (1), 6, 7-dimethoxycoumarin (2), indole-3-aldehyde (3), S-(+)-dehydrovomifoliol (4), loliolide (5), magnolol (6), trans-p-coumaryl aldehyde (7), honokiol (8), 4-allylphenol (9), nonacosanoic acid (10), grasshopper ketone (11), and syringin (12). Conclusion: Compounds 1-5, 7, 9-11 are first isolated from the leaves of M. officinalis var. biloba and plants of this genus.