Studies on Electrode Kinetics of Mixed Legand Complexes of Mn (11) In Dioxan At DME.

ABSTRACT

Mixed ligand complexes of Mn (11) with pyridines and halides and pseudohalides have been synthesised. The reduction of synthesised complexes at dropping mercury electrode in various percentage of dioxan have been studied. The reductions are diffusion controlled. Slope values indicate reduction to be irrversible. Kinetic parameters [K0 fh,αn &ε] have been calculated by Meites Isreal and Gaur Bhargava Methods. The effects of various compositions of dioxan have been investigated.