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1.
Heliyon ; 9(4): e15552, 2023 Apr.
Article in English | MEDLINE | ID: mdl-37151688

ABSTRACT

With the aim of exploring the possibility of achieving a low-cost thermal spray coating to prevent wear, erosion and corrosion. In the current study, flyash-Al2O3 and flyash-SiC composite coatings were effectively created using the air plasma spray process on substrates of Al6061 alloy. NiCr material is used as the bond coat to improve the bond strength between the coat and the substrate. Taguchi's DoE method is applied to for spray process parameters optimization. In addition, the developed coating is subjected to microstructure analysis and long-term immersion corrosion testing (1 year) in an aqueous environment to assess corrosion properties. The results revealed that the over a certain test period, the developed flyash-SiC coating has greater corrosion resistance than the uncoated and flyash-Al2O3 coated Al6061. It is noticed that the corrosion resistance of the flyash-Al2O3 coating shifts to a negative value with respect to the uncoated substrate. The uncoated sample is extensively pitted and locally corroded, as shown by the SEM image of the corroded surface. Flyash-corroded Al2O3's surface exhibits extensive degradation in the form of peeling, breaking, and cracking of the splats. With flyash-SiC composite coating a very minor corrosion splat deterioration is seen.

2.
Heliyon ; 9(4): e14807, 2023 Apr.
Article in English | MEDLINE | ID: mdl-37077675

ABSTRACT

This study presents the details of performance and exergy investigations on an inclined solar still with baffle arrangements. The shortage of consumable water creates the transformation of accessible brackish water into consumable water an unavoidable one and this can be accomplished utilizing sun-oriented refining. To remove drinkable water from pungent water, sun-oriented still is broadly utilized. To build the contact season of the pungent water with sunlight-based brilliance, perplex course of action is set to expand the opposition in the stream. This prompts more vanishing of brackish water. Therefore, the objective of this study is to improve freshwater yield. The experimental study is performed for two different mass flow rates (mf1 = 0.0833 kg/min and mf2 = 0.166 kg/min). An increase in the mass flow of water directly deteriorates the yield of fresh water. Highest accumulated freshwater yield is achieved as 2.908 kg/m2 day during the month of May for mf1 = 0.0833 kg/min. The accumulated freshwater yield improved by 4.23% in comparison with inclined solar still designs. Moreover, the yield is better by 3.49%-61.56% in comparison with various solar still designs. Using RSM, a polynomial statistical model is specified to estimate as well as maximize the freshwater yield of ISSB. The exergy analysis for mf1 = 0.0833 kg/min shows a maximum hourly exergy efficiency of 6.82%.

3.
Bioinorg Chem Appl ; 2022: 7470263, 2022.
Article in English | MEDLINE | ID: mdl-35959227

ABSTRACT

Industrial wastes contain more toxins that get dissolved in the rivers and lakes, which are means of freshwater reservoirs. The contamination of freshwater leads to various issues for microorganisms and humans. This paper proposes a novel method to remove excess copper from the water. The nanotubes are used as a powder in membrane form to remove the copper from the water. The multiwalled carbon nanotube is widely used as a membrane for filtration. It contains many graphene layers of nm size that easily adsorbs the copper when the water permeates through it. Activated carbon is the earliest and most economical method that also adsorbs copper to a certain extent. This paper proposes the methods of involving the activated carbon in the multiwalled carbon nanotube to improve the adsorption capability of the copper. Here, activated carbon is impregnated on the multiwalled carbon nanotube's defect and imperfect surface areas. It makes more adsorption sites on the surface, increasing the adsorption amount. The same method is applied to Hydroxyl functionalized multiwalled carbon nanotubes. Both the methods showed better results and increased the copper removal. The functionalized method removed 93.82% copper, whereas the nonfunctionalized method removed 80.62% copper from the water.

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