Influence of Surface-Active Substances and Substrates on the Wettability of Individual Aerosol Particles during Condensation by Environmental Scanning Electron Microscopy.

The formation of liquid cloud droplets from aerosol particles in the Earth atmosphere is still under debate particularly because of the difficulties to quantify the importance of bulk and surface effects in these processes. Recently, single-particle techniques have been developed to access experimental key parameters at the scale of individual particles. Environmental scanning electron microscopy (ESEM) has the advantage to provide in situ monitoring of the water uptake of individual microscopic particles deposited on solid substrates. In this work, ESEM was used to compare droplet growth on pure ammonium sulfate (NH4)2SO4 and mixed sodium dodecyl sulfate/ammonium sulfate (SDS/(NH4)2SO4) particles and to explore the role of experimental parameters, such as the hydrophobic-hydrophilic character of the substrate, on this growth. With hydrophilic substrates, the growth on pure salt particles was strongly anisotropic, but this anisotropy was suppressed by the presence of SDS. With hydrophobic substrates, it is the wetting behavior of the liquid droplet that is impacted by the presence of SDS. The wetting behavior of the pure (NH4)2SO4 solution on a hydrophobic surface shows a step-by-step mechanism that can be attributed to successive pinning-depinning phenomena at the triple-phase line frontier. Unlike the pure (NH4)2SO4 solution, the mixed SDS/(NH4)2SO4 solution did not show such a mechanism. Therefore, the hydrophobic-hydrophilic character of the substrate plays an important role in the stability and dynamics of the liquid droplets' nucleation by water vapor condensation. In particular, hydrophilic substrates are not suited for the investigation of the hygroscopic properties (deliquescence relative humidity (DRH) and hygroscopic growth factor (GF)) of particles. Using hydrophobic substrates, data show that the DRH of (NH4)2SO4 particles is measured within 3% accuracy on the RH and their GF could indicate a size-dependent effect in the micrometer range. The presence of SDS does not seem to modify the DRH and GF of (NH4)2SO4 particles. This study shows that the water uptake on deposited particles is a complex process but, once carefully taken into account, ESEM is a suitable technique to study them.

Promoter Effect of Early Stage Grown Surface Oxides: A Near-Ambient-Pressure XPS Study of CO Oxidation on PtSn Bimetallics.

The knowledge of the catalyst active phase on the atomic scale under realistic working conditions is the key for designing new and more efficient materials. In this context, the investigation of CO oxidation on the bimetallic Pt3Sn(111) surfaces by near-ambient-pressure X-ray photoelectron spectroscopy and density functional theory calculations illustrates how combining advanced methodologies allows the determination of the nature of the active phase. Starting from 300 K and 500 mTorr of oxygen, the progressive formation of surface oxides is observed with increasing temperature: SnO, PtO units first, and SnO2, PtO2 units afterward. For CO oxidation on the (2 × 2) surface, the activity gain is assigned to the build-up of ultrathin domains composed of SnO and SnO2 units. The formation of these early stage surface oxides is entirely supported by a density functional theory analysis. More generally, this study demonstrates how the catalyst surface oxidation and transformation can be better controlled by a relevant choice of environmental conditions.