Magnetic and structural properties of the solid solution CuAl2(1-x)Ga2xO4.

CuAl2O4 is a ternary oxide spinel with Cu2+ ions ([Formula: see text]) primarily populating the A-site diamond sublattice. The compound is reported to display evidence of spin glass behavior but possess a non-frozen magnetic ground state below the transition temperature. On the other hand, the spinel CuGa2O4 displays spin glass behavior at ~ 2.5 K with Cu2+ ions more readily tending to the B-site pyrochlore sublattice. Therefore, we investigate the magnetic and structural properties of the solid solution CuAl2(1-x)Ga2xO4 examining the evolution of the magnetic behavior as Al3+ is replaced with a much larger Ga3+ ion. Our results show that the Cu2+ ions tend to migrate from tetrahedral to octahedral sites as the Ga3+ ion concentration increases, resulting in a concomitant change in the glassy magnetic properties of the solution. Results indicate glassy behavior for much of the solution with a general trend towards decreasing magnetic frustration as the Cu2+ ion shifts to the B-site. However, the [Formula: see text] and 0.2 members of the system do not show glassy behavior down to our measurement limit (1.9 K) suggesting a delayed spin glass transition. We suggest that these two members are additional candidates for investigation to access highly frustrated exotic quantum states.

Prediction of antiferromagnetism in barium chromium phosphide confirmed after synthesis.

We have carried out density-functional theory (DFT) calculations for the chromium pnictide BaCr2P2, which is structurally analogous to BaFe2As2, a parent compound for iron-pnictide superconductors. Evolutionary methods combined with DFT predict that the chromium analog has the same crystal structure as the latter. DFT also predicts Néel antiferromagnetic order on the chromium sites. Comparison with a simple electron-hopping model over a square lattice of chromium atoms suggests that it is due to residual nesting of the Fermi surfaces. We have confirmed the DFT predictions directly after the successful synthesis of polycrystalline samples of BaCr2P2. X-ray diffraction recovers the predicted crystal structure to high accuracy, while magnetic susceptibility and specific-heat measurements are consistent with a transition to an antiferromagnetically ordered state below [Formula: see text] K.

Effect of a compressive uniaxial strain on the critical current density of grain boundaries in superconducting YBa2Cu3O7-delta films.

The mechanism by which grain boundaries impede current flow in high-temperature superconductors has resisted explanation for over two decades. We provide evidence that the strain fields around grain boundary dislocations in YBa2Cu3O7-delta thin films substantially suppress the local critical current density Jc. The removal of strain from the superconducting grain boundary channels by the application of compressive strain causes a remarkable increase in Jc. Contrary to previous understanding, the strain-free Jc of the grain boundary channels is comparable to the intrinsic Jc of the grains themselves.