RESUMEN
A cobalt oxide-based oxygen-evolving cocatalyst (Co-Pi) is photodeposited by visible-light irradiation onto nanocrystalline TiO(2)-polyheptazine (TiO(2)-PH) hybrid photoelectrodes in a phosphate buffer. The Co-Pi cocatalyst couples effectively to photoholes generated in the surface polyheptazine layer of the TiO(2)-PH photoanode, as evidenced by complete photooxidation of water to oxygen under visible-light (λ>420 nm) irradiation at moderate bias potentials. In addition, the presence of the cocatalyst also reduces significantly the recombination of photogenerated charges, particularly at low bias potentials, which is ascribed to better photooxidation kinetics resulting in lower accumulation of holes. This suggests that further improvements of photoconversion efficiency can be achieved if more effective catalytic sites for water oxidation are introduced to the surface structure of the hybrid photoanodes.
RESUMEN
We investigated photoelectrodes based on TiO(2)-polyheptazine hybrid materials. Since both TiO(2) and polyheptazine are extremely chemically stable, these materials are highly promising candidates for fabrication of photoanodes for water photooxidation. The properties of the hybrids were experimentally determined by a careful analysis of optical absorption spectra, luminescence properties and photoelectrochemical measurements, and corroborated by quantum chemical calculations. We provide for the first time clear experimental evidence for the formation of an interfacial charge-transfer complex between polyheptazine (donor) and TiO(2) (acceptor), which is responsible for a significant red shift of absorption and photocurrent response of the hybrid as compared to both of the single components. The direct optical charge transfer from the HOMO of polyheptazine to the conduction band edge of TiO(2) gives rise to an absorption band centered at 2.3 eV (540 nm). The estimated potential of photogenerated holes (+1.7 V vs. NHE, pH 7) allows for photooxidation of water (+0.82 V vs. NHE, pH 7) as evidenced by visible light-driven (λ > 420 nm) evolution of dioxygen on hybrid electrodes modified with IrO(2) nanoparticles as a co-catalyst. The quantum-chemical simulations demonstrate that the TiO(2)-polyheptazine interface is a complex and flexible system energetically favorable for proton-transfer processes required for water oxidation. Apart from water splitting, this type of hybrid materials may also find further applications in a broader research area of solar energy conversion and photo-responsive devices.
RESUMEN
Surface-modified TiO2 photocatalysts were synthesized by a photosynthetic route involving visible-light-induced (λ>455â nm) activation of benzene and toluene at the surface of TiO2 leading to the formation of carbonaceous polymeric deposits. IR spectroscopic and photoelectrochemical experiments showed that the mechanism of the photosynthetic reactions involves intra-bandgap surface states at TiO2 related to surface OH groups interacting with adsorbed aromatic molecules. The photosynthesized surface-modified TiO2 materials exhibited enhanced activity, relative to pristine TiO2 , in photocatalytic degradation (and complete mineralization) of 4-chlorophenol. The improvement was pronounced particularly under visible-light (λ>455â nm) irradiation with the relative initial photodegradation rate enhanced by a factor of four. The surface-modified photocatalysts exhibited good stability under the operating conditions, and the optimum carbon content was approximately 0.5â wt %. Mechanistic studies showed that the enhanced visible-light photodegradation of 4-chlorophenol is due to modified surface-adsorption properties that facilitate formation of a surface complex between titania and 4-chlorophenol, rather than due to any sensitizing effect of the carbonaceous deposits. The study highlights the importance of considering the interaction between pollutant molecules and the photocatalyst surface in heterogeneous photocatalysis, and possibly opens up a route for photosynthesis of further surface-modified photocatalysts with tuned surface properties.
RESUMEN
Benzene can be activated by visible light (λ > 455 nm) in the presence of TiO(2), which leads to formation of carbonaceous polymeric deposits on the titania surface. These photosynthesized surface-modified materials exhibit enhanced photoactivity in degradation of phenolic compounds, particularly under visible light irradiation.