Synthesis of Aminomethylpyridine-Decorated Polyamidoamine Dendrimer/Apple Residue for the Efficient Capture of Cd(II).

Water contamination irritated by Cd(II) brings about severe damage to the ecosystem and to human health. The decontamination of Cd(II) by the adsorption method is a promising technology. Here, we construct aminomethylpyridine-functionalized polyamidoamine (PAMAM) dendrimer/apple residue biosorbents (AP-G1.0-AMP and AP-G2.0-AMP) for adsorbing Cd(II) from aqueous solution. The adsorption behaviors of the biosorbents for Cd(II) were comprehensively evaluated. The maximum adsorption capacities of AP-G1.0-AMP and AP-G2.0-AMP for Cd(II) are 1.40 and 1.44 mmol·g-1 at pH 6. The adsorption process for Cd(II) is swift and can reach equilibrium after 120 min. The film diffusion process dominates the adsorption kinetics, and a pseudo-second-order model is appropriate to depict this process. The uptake of Cd(II) can be promoted by increasing concentration and temperature. The adsorption isotherm follows the Langmuir model with a chemisorption mechanism. The biosorbents also display satisfied adsorption for Cd(II) in real aqueous media. The adsorption mechanism indicates that C-N, N═C, C-O, CONH, N-H, and O-H groups participate in the adsorption for Cd(II). The biosorbents display a good regeneration property and can be reused with practical value. The as-prepared biosorbents show great potential for removing Cd(II) from water solutions with remarkable significance.

Mechanical Properties of Low-Molecular-Weight Peptide Hydrogels Improved by Thiol-Ene Click Chemistry.

Low-molecular-weight peptide hydrogels can be formed by self-assembly through weak interactions, but the application of the hydrogel is influenced by its weak mechanical properties. Therefore, it is important to construct low-molecular-weight peptide hydrogels with excellent mechanical properties. In this work, we designed the pentapeptide molecule Fmoc-FFCKK-OH (abbreviated as FFCKK) with a sulfhydryl group, and another low-molecular-weight cross-linker N,N'-methylenebis(acrylamide) (MBA) was introduced to construct a hydrogel with excellent mechanical properties. The secondary structure change process of FFCKK and the assembly mechanism of hydrogel were analyzed using theoretical calculations and experimental characterizations. The occurrence of thiol-ene click chemistry provides covalent interaction in the hydrogel, and the synergistic effect ofcovalent interaction and hydrogen bonding improves the mechanical properties of the hydrogel by nearly 10-fold. The hydrogel was observed to be able to withstand a stress of 368 Pa and to break in a layer-by-layer manner by compression testing. The micromechanics of the hydrogels were characterized, and the excellent mechanical properties of the hydrogels were confirmed. The synergistic approach provides a new idea for the preparation of low-molecular-weight peptide hydrogels and facilitates the expansion of their potential applications in biomedical fields.

Adsorption Performance of Magnetic Covalent Organic Framework Composites for Bisphenol A and Ibuprofen.

As typical environmental endocrine disruptors and nonsteroidal anti-inflammatory drugs, bisphenol A and ibuprofen in water supplies can cause great harm to the ecological environment and human health. In this study, magnetic covalent organic framework composites Fe3O4@COF-300 were synthesized by the hydrothermal method and used to remove bisphenol A and ibuprofen from water. Fe3O4@COF-300 could be rapidly separated from the matrix by external magnetic fields, and could selectively adsorb bisphenol A and ibuprofen in the presence of coexisting compounds such as phenol, Congo red, and amino black 10B. The removal efficiency of ibuprofen was 96.12-98.52% at pH in the range of 2-4 and that of bisphenol A was 92.18-95.62% at pH in the range of 2-10. The adsorption of bisphenol A and ibuprofen followed a pseudo-second-order kinetic and Langmuir model, and was a spontaneous endothermic process with the maximum adsorption amounts of 173.31 and 303.03 mg∙g-1, respectively. The material presented favorable stability and reusability, and the removal efficiency of bisphenol A and ibuprofen after 5 cycles was still over 92.15% and 89.29%, respectively. Therefore, the prepared composite Fe3O4@COF-300 exhibited good performance in the adsorption of bisphenol A and ibuprofen in water.

Direct Synthesis of Sulfur-Decorating PAMAM Dendrimer/Mesoporous Silica for Enhanced Hg(II) and Cd(II) Adsorption.

Water security caused by heavy metals poses a deleterious hazard to public health and the ecological system. The construction of adsorbents by polyamidoamine (PAMAM) dendrimers for efficient removal of metal ions has attracted considerable interest. However, the general method for the fabrication of these adsorbents was achieved by the surface chemical modification of the substrates with PAMAM dendrimer, which usually causes the defects of low density and uneven distribution of the dendrimer, the blocking of pores, and reducing the adsorption performance. Hence, the development of a new method for preparation of PAMAM dendrimer-based adsorbent to realize the efficient and enhanced adsorption of metal ions is still a challenge. Herein, methylisothiocyanate decorated PAMAM dendrimer/mesoporous silica composites (G0-S-1/x, G1.0-S-1/x, G2.0-S-1/x, x = 2, 4, 6, 8, 10) were synthesized by the direct sol-gel reaction of alkoxysilyl-containing functional PAMAM dendrimer. The adsorbents display enhanced adsorption property for Hg(II) and Cd(II) as compared with the same adsorbents which were prepared by traditional chemical modification method. Take G2.0-S-1/2 as an example, the maximum adsorption capacities are 2.41 and 0.87 mmol·g-1 for Hg(II) and Cd(II), respectively . Moreover, the adsorbents show excellent selective adsorption and regeneration property. G2.0-S-1/2 displays distinct selectivity for Hg(II) with the presence of Co(II), Pb(II), Cd(II), and Cu(II). The regeneration percentage still maintains 95.2% after five adsorption-desorption cycles. The adsorption mechanism is also certified by the experimental method and theoretical calculation.

Peptide Hydrogel with Antibacterial Performance Induced by Rare Earth Metal Ions.

Metal ion-induced peptide assembly is an interesting field. As compared to traditional antibacterial Ag+, rare earth metal ions possess the advantage of antibacterial performance with photostability and low toxicity. Herein, a new peptide Fmoc-FFWDD-OH was designed and synthesized, which could form a stable hydrogel induced by rare earth metal ions, including Tb3+, Eu3+, and La3+. The mechanical properties were characterized by rheological measurements, and they exhibited elasticity-dominating properties. Transmission electron microscopy (TEM) images showed a large number of nanoscale fiber structures formed in the hydrogel. Circular dichroism (CD) spectra, Fourier transform infrared (FT-IR) spectra, ThT assays, and X-ray diffraction (XRD) pattern illustrated the formation mechanism of the fiber structure. The rare earth ion-induced peptide hydrogel was proved to possess good antibacterial performance on Escherichia coli (E. coli) with excellent biocompatibility. The introduction of rare earth metal ions may have some potential applications in the biological antibacterial and medical fields.

Drosera-Inspired Dual-Actuating Double-Layer Hydrogel Actuator.

Drosera is a small insectivorous plant whose antennae can fold up, encircle, and prey. The rapid movement of the antennae is achieved by the synergistic effect of a double-layer structure with the antennae contracts on the front and expands on the back. In this work, a drosera-inspired dual-actuating double-layer hydrogel actuator is proposed, in which the temperature-responsive poly(N, N-diethyl acrylamide) (PDEAAm) layer acts as the main actuation layer and a moisture-responsive poly(acrylamide) (PAAm) layer acts as the auxiliary actuation layer. In a water environment with low temperature, both the PAAm and PDEAAm layers absorb water and expand with a swelling property. When the temperature exceeds the lower critical solution temperature of PDEAAm, the PDEAAm layer undergoes a hydrophilic-hydrophobic transition and shrinks rapidly. Therefore, the synergistic effect of the double-layer hydrogel enables the double-layer hydrogel to achieve a large bending angle at high temperature. In addition, when designing and fabricating shape-patterned double-layer hydrogels, complex shape changes can be achieved. Due to the physical and chemical properties, the actuator can be used to grab, transport, and release objects. This drosera-inspired double-layer hydrogel actuator has high practical value, which may provide new insights for the design and manufacture of artificial intelligence materials.

Single network double cross-linker (SNDCL) hydrogels with excellent stretchability, self-recovery, adhesion strength, and conductivity for human motion monitoring.

Hydrogels, as a kind of soft materials, are good candidates for smart skin-like materials. A double network is usually fabricated to improve the mechanical properties of hydrogels, and involves two different kinds of networks. In this work, a novel strategy for preparing single network double cross-linker (SNDCL) hydrogels was proposed and the prepared hydrogels exhibited excellent mechanical properties, including stretchability, compressibility, self-recovery, adhesion, shape memory and mechanical strength. N,N'-Methylenebisacrylamide forms covalent bonds with the network, while citric acid can form multiple weak interactions due to the polycarboxylic structure. This improves the tensile properties (6564%) and compressive properties of the hydrogel, and the hydrogels also exhibit long-lasting self-adhesion ability on various substrates. In addition, the hydrogels with multiple properties can be used as flexible strain sensors, allowing the monitoring of body movements. The hydrogels can hopefully be used in wearable electronic sensor devices and for healthcare monitoring.

Removal of Cd(II) and Fe(III) from DMSO by silica gel supported PAMAM dendrimers: Equilibrium, thermodynamics, kinetics and mechanism.

A series of silica gel supported amino-terminated PAMAM dendrimers (SG-G1.0 - SG-G3.0) were used for the removal of Cd(II) and Fe(III) from dimethylsulfoxide (DMSO). Various parameters that influence adsorption behaviors including temperature, contact time, and initial metal ion concentration were studied. The adsorption mechanism was revealed by combining the results of experiment and density functional theory (DFT) calculation. It indicates that the adsorption capacities for Cd(II) and Fe(III) are largest among the metal ions tested. The adsorption capacity of SG-G1.0 - SG-3.0 for Cd(II) and Fe(III) follows the order of SG-G2.0 > SG-3.0 > SG-G1.0. The adsorption isotherm shows the adsorption capacities for both metal ions increases with raising the temperature and initial metal ion concentration. The adsorption isotherm is consistent with Langmuir model and the adsorption process is dominated by chemical adsorption mechanism. Thermodynamic parameters indicates that the adsorption for both Cd(II) and Fe(III) is spontaneous and endothermic. Kinetic adsorption indicates that the adsorption equilibrium times for Cd(II) and Fe(III) is about 200 and 350 min, respectively, which can be described by a pseudo-second-order model and controlled by film diffusion process. FTIR analysis and theoretical calculation revealed that the carbonyl O atoms, secondary amine N atoms, and primary amine N atoms are the primary factor responsible for PAMAM adsorption by forming tetra- and penta-coordinated chelates with metal ions.

Multiperformance PAM/PVA/CaCO3 Hydrogel for Flexible Sensing and Information Encryption.

Currently, the development of hydrogels with excellent mechanical properties (elasticity, fatigue resistance, etc.) and conductive properties can better meet their needs in the field of flexible sensor device applications. Generally, hydrogels with a denser cross-linking density tend to have better mechanical properties, but the improvement in mechanical properties comes at the expense of reduced electrical conductivity. Directly generating CaCO3 in the hydrogel prepolymer can not only increase the cross-linking density of its network but also introduce additional ions to enhance its internal ionic strength, which is beneficial to improving the conductivity of the hydrogel. It is still a big challenge to directly generate CaCO3 in the static prepolymer solution and ensure its uniform dispersion in the hydrogel. Herein, we adopted an improved preparation method to ensure that the directly generated CaCO3 particles can be evenly dispersed in the static prepolymer solution until the polymerization is completed. Finally, a PAM/PVA/CaCO3 hydrogel with supertensile, compressive, toughness, and fatigue resistance properties was prepared. In addition, the presence of free Na+ and Cl- gives the hydrogel excellent conductivity and sensing performance to monitor daily human activities. On the basis of the application of hydrogels in information communication, we have further deepened this application by combining the characteristics of hydrogels themselves. Combined with ASCII code, the hydrogel can also be applied in information exchange and information encryption and decryption, achieving the antitheft function in smart locks. A variety of excellent performance integrated PAM/PVA/CaCO3 hydrogels have broad application prospects for flexible sensors, highlighting great potential in human-computer interaction and intelligent information protection.

Synthesis of salicylaldehyde tailored PAMAM dendrimers/chitosan for adsorption of aqueous Hg(II): Performance and mechanism.

Water pollution caused by Hg(II) exerts hazardous effect to environmental safety and human health. Herein, a family of salicylaldehyde tailored poly(amidoamine) (PAMAM) dendrimers/chitosan composites (G0-S/CTS, G1-S/CTS, and G2-S/CTS) were prepared and used for the removal of Hg(II) from water solution. The adsorption performance of the as-prepared composites for Hg(II) was thoroughly demonstrated by determining various influencing factors. G0-S/CTS, G1-S/CTS and G2-S/CTS exhibited competitive adsorption capacity and good adsorption selective property for Hg(II). The maximum adsorption capacity of G0-S/CTS, G1-S/CTS and G2-S/CTS for Hg(II) were 1.86, 2.18 and 4.47 mmol‧g-1, respectively. The adsorption for Hg(II) could be enhanced by raising initial Hg(II) concentration and temperature. The adsorption process was dominated by film diffusion processes with monolayer adsorption behavior. The functional groups of NH2, CONH, CN, OH, CO and CN were mainly responsible for the adsorption of Hg(II). G0-S/CTS, G1-S/CTS and G2-S/CTS displayed good regeneration property and the regenerate rate maintained 95.00 % after five adsorption-desorption cycles. The as-prepared adsorbents could be potentially used for the efficient removal of Hg(II) from aqueous solution.

Synthesis of hyperbranched polyamine dendrimer/chitosan/silica composite for efficient adsorption of Hg(II).

The pollution of water system with Hg(II) exerts hazardous effect to ecosystem and public health. Adsorption is considered to be a promising strategy to remove Hg(II) from aqueous solution. Herein, hyperbranched polyamine dendrimer/chitosan/silica composite (SiO2-FP) was synthesized for the adsorption of aqueous Hg(II). The adsorption performance of SiO2-FP was comprehensively determined by considering various influencing factors. SiO2-FP displays good adsorption performance for Hg(II) with the adsorption capacity of 0.79 mmol·g-1, which is higher than the corresponding chitosan functionalized silica (SiO2-CTS) by 46.30 %. The optimal solution pH for the adsorption of Hg(II) is 6. Adsorption kinetic indicates the adsorption for Hg(II) can reach equilibrium at 250 min. Adsorption kinetic process can be well fitted by pseudo-second-order (PSO). Adsorption isotherm reveals the adsorption for Hg(II) can be promoted by increasing initial Hg(II) concentration and adsorption temperature. The adsorption isotherm indicates the adsorption process can be described by Langmuir model and the adsorption is a spontaneous, endothermic and entropy-increased process. SiO2-FP displays excellent adsorption selectivity and can 100 % adsorb Hg(II) with the coexisting of Ni(II), Zn(II), Pb(II), Mn(II), and Co(II). Adsorption mechanism demonstrates -NH-, -NH2, CN, CONH, -OH, and CO participated in the adsorption. SiO2-FP exhibits good regeneration property and the regeneration rate can maintain approximately 90 % after five adsorption-desorption cycles.

Feasible synthesis of bifunctional polysilsesquioxane microspheres for robust adsorption of Hg(II) and Ag(I): Behavior and mechanism.

The pollution of Hg(II) and Ag(I) to water system exerts hazardous effect to aquatic ecosystem and public security. Simple strategy for constructing adsorbents to efficient remove them is greatly desired. Thus, a series of thiol and amino groups containing bifunctional polysilsesquioxanes (ASPSS) microspheres with adjustable porous structure and functional group content were synthesized by one-step feasible sol-gel process. The adsorption behavior and mechanism of ASPSS microspheres toward Hg(II) and Ag(I) was thoroughly determined. The maximum adsorption capacity of ASPSS for Hg(II) and Ag(I) are 4.32 and 3.86 mmol·g-1 under 25 â„ƒ. The as-prepared ASPSS microspheres can 100% selectively capture Hg(II) with the coexisting of Mn(II), Co(II), Pb(II), Cd(II), Cu(II), Fe(III). And they can 100% adsorb Ag(I) with the presence of Cd(II), Pb(II), Co(II), Ni(II), and Zn(II). Moreover, the ASPSS microspheres exhibit good removal efficiency for Hg(II) and Ag(I) from simulated industrial wastewater with the coexistence of multiple pollutants. Adsorption mechanism suggests the adsorption for Hg(II) and Ag(I) is the synergistic coordination effect of amino and thiol groups. The excellent adsorption selectivity for Hg(II) and Ag(I) is attributed to the super binding ability of these functional group. ASPSS microspheres also exhibit good regeneration ability and could be reused for removing Hg (II) and Ag(I) from aqueous solution with practical value.

Synthesis of functional poly(amidoamine) dendrimer decorated apple residue cellulose for efficient removal of aqueous Hg(II).

Water pollution caused by Hg(II) exerts hazardous effect to the environment and public health. The design and fabrication of eco-friendly bioadsorbents for efficient removal of Hg(II) from aqueous solution is a promising strategy. Herein, a series of bioadsorbents were synthesized by the decoration of apple residue cellulose with different generation (G) Schiff base functionalized poly(amidoamine) (PAMAM) dendrimers (SA-G0/CE, SA-G1.0/CE and SA-G2.0/CE). The structures of SA-G0/CE, SA-G1.0/CE and SA-G2.0/CE were characterized and their adsorption performances were determined comprehensively by considering various factors. The maximum adsorption capacity of SA-G0/CE, SA-G1.0/CE and SA-G2.0/CE for Hg(II) are 1.18, 1.73 and 1.88 mmol·g-1, respectively. The as-prepared bioadsorbents exhibit competitive adsorption capacity as compared with other reported adsorbents. Moreover, they exhibit remarkable adsorption selectivity toward Hg(II) with the coexistence of Ni(II), Cd(II), Mn(II), or Pb(II). The bioadsorbents display satisfactory adsorption performance in real water sample and can be reused with good regeneration property. Adsorption mechanism reveals that the functional groups of OH, -CONH-, CN and NC take part in the adsorption for Hg(II). The work not only opens a pathway to realize the reuse of apple residue, but also provides a promising strategy to construct efficient bioadsorbents for the decontamination of Hg(II) from aqueous solution.

Oxidized sodium alginate/polyacrylamide hydrogels adhesive for promoting wheat growth.

Chemical modification of sodium alginate (SA) polymer chains can increase its functional group species. Sodium periodate (SP) was usually used to oxidize the hydroxyl groups on the chain of SA to aldehyde groups, the preparation of oxidized sodium alginate (OSA) using SP is not only complicated, also limits the variety of functional groups on the chain of OSA. By contrast, we have developed an innovative strategy for OSA, in which ammonium persulfate (APS) was used to oxidize SA, providing a clear elucidation of the oxidizing process and mechanism. OSA/PAM hydrogels were synthesized using OSA, the hydrogels possess excellent adhesion properties to various non-metallic and metallic substrates. Tensile and compression tests show that the cross-linked OSA/PAM hydrogels have superior mechanical properties. We exploit OSA/PAM hydrogels as soil adhesive and water-retaining agents for wheat growth. OSA/PAM hydrogels significantly improve the survival time of wheat grown in brown loam soil under a water-shortage environment, and slow down the wilting of wheat in a water-shortage environment and prolong the survival time of wheat in sandy soils. Our trials should make hydrogels important for wheat cultivation in brown loam soils and the development of desert areas.

Advances of peptides for antibacterial applications.

In the past few decades, peptide antibacterial products with unique antibacterial mechanisms have attracted widespread interest. They can effectively reduce the probability of drug resistance of bacteria and are biocompatible, so they possess tremendous development prospects. This review provides recent research and analysis on the basic types of antimicrobial peptides (including poly (amino acid)s, short AMPs, and lipopeptides) and factors to optimize antimicrobial effects. It also summarizes the two most important modes of action of antimicrobial peptides and the latest developments in the application of AMPs, including antimicrobial agent, wound healing, preservative, antibacterial coating and others. Finally, we discuss the remaining challenges to improve the antibacterial peptides and propose prospects in the field.

Surface-initiated PET-ATRP and mussel-inspired chemistry for surface engineering of MWCNTs and application in self-healing nanocomposite hydrogels.

A green strategy by integrating surface-initiated metal-free photoinduced electron transfer-atom transfer radical polymerization (PET-ATRP) with mussel-inspired polydopamine (PDA) chemistry, was used to fabricate multi-walled carbon nanotubes (MWCNTs)/poly(4-vinylpyridine) (P4VP) nanocomposites. Self-healing nanocomposite hydrogels were facilely designed with these nanocomposites through dynamic supramolecular interactions. Using mussel-inspired PDA chemistry from MWCNTs, nanocomposites (MWCNTs@PDA-P4VP) were successfully prepared by metal-free PET-ATRP with MWCNTs@PDA-Br as an initiator, rhodamine B as photocatalyst, 4-vinylpyridine (4VP) as monomer, respectively. Importantly, the obtained nanocomposite hydrogels had high mechanical strength (2.9 MPa), prior fracture strain (633.8%) and excellent self-healing property (90.6%). These methodologies will provide opportunities for the design of eco-functional materials or flexible biosensors.

Electronic structures of bis- and monothiophene complexes with Fe, Co, Ni: a density functional theory study.

A density functional theory study for the bis- and monothiophene complexes of Fe, Co, and Ni (MT2 and MT, T = thiophene, M = Fe, Co, Ni) was performed to understand their coordination geometries, bonding properties, vibration spectra and singlet excited state spectra. The typical metal coordination exists in the complexes. The Fe-thiophene coordination has the highest stability, with Ni-thiophene being the second highest, and Co-thiophene the lowest. Bisthiophene complexes of Co and Ni prefer to homolytically dissociate to their monothiophene ones and free thiophene. Frequency calculation shows that the ligand-M-ligand asymmetric stretching vibration in bisthiophene complexes shows a strong absorption, at 435.2, 495.7, and 383 cm(-1) for Fe(eta4-T)2, Co(eta2-T)2 and Ni(eta2-T)2, respectively. The M-S stretching vibration in monothiophene complexes shows a strong absorption in the far-infrared region, at 209, 156, and 150 cm(-1) for Fe(eta4-T), Co(eta4-T) and Ni(eta5-T), respectively. The excited state spectra indicate that the characteristic absorption wavelengths of the complexes have a red shift of more than 12.40 eV compared to free thiophene, at 3.54, 1.64, 3.83, 2.75, 1.43, and 2.58 eV for Fe(eta4-T)2, Co(eta2-T)2, Ni(eta2-T)2, Fe(eta4-T), Co(eta4-T), and Ni(eta5-T), respectively.

Comparison of synthesis of chelating resin silica-gel-supported diethylenetriamine and its removal properties for transition metal ions.

Four kinds of silica-gel (SG)-supported diethylenetriamine (DETA) chelating resins SG-DETA-1, SG-DETA-2, SG-DETA-3, and SG-DETA-4 were prepared by functionalization of silica-gel via so-called "heterogeneous-direct-amination" (hetero-DA), "homogeneous-direct-amination" (homo-DA), "heterogeneous end-group protection" (hetero-EGP), and "homogeneous end-group protection" (homo-EGP) routes, respectively. These functionalized reactions on silica-gel were confirmed through elemental analysis, infrared spectroscopy, X-ray diffractometry, porous analysis, and thermogravimetry. Element analysis revealed that the direct-amination routes and homogeneous condition were more beneficial than the corresponding end-group protection routes and heterogeneous condition to the syntheses of chelating resins with high N content. Several metal ions, such as Ag(+), Cu(2+), Ni(2+), Hg(2+), Zn(2+) and Pb(2+), were chosen as representatives to investigate the relationship between adsorption capacities and N content of ligands onto the surface of silica-gel. The experiments results showed that all resins, SG-DETA-1, SG-DETA-2, SG-DETA-3 and SG-DETA-4, had a better adsorption for Hg(2+) and Cu(2+) than others. One conclusion should be drawn from the above compared experiments, that is, higher N content of silica-gel resins does not ensure a higher utilization ratio of N.

Removal of Cr(III) from aqueous solution by silica-gel/PAMAM dendrimer hybrid materials.

Water pollution caused by Cr(III) is a serious environmental problem which bring adverse effect to environmental protection and public safety. Efficient removal of Cr(III) from aqueous solution is important for the remediation of Cr(III) pollution. Herein, a series of silica-gel/polyamidoamine (PAMAM) dendrimer hybrid materials (SG-G0~SG-G4.0) were used for the removal of Cr(III) from aqueous solution. The factors that affect the adsorption were extensively studied and the adsorption mechanism was demonstrated based on the experimental results and density functional theory (DFT) calculation. Result demonstrates the adsorption capacity of ester-terminated silica-gel/PAMAM dendrimers follow the order of SG-G2.5 > SG-G3.5 > SG-G1.5 > SG-G0.5, while that of amino-terminated ones decrease in the order of SG-G2.0 > SG-G4.0 > SG-G3.0 > SG-G1.0 > SG-G0. The highest adsorption is achieved at pH 4.0 for both ester- and amino-terminated materials. Adsorption kinetic indicates the adsorption equilibrium can be reached at about 240 and 180 min for amino- and ester-terminated hybrids, respectively. Adsorption kinetic can be well fitted by pseudo-second-order kinetic model with film diffusion process as the rate-limiting step. Adsorption isotherm follows Langmuir model with monolayer adsorption behavior. Fourier transform infrared spectra (FTIR) indicate the adsorption of Cr(III) by PAMAM dendrimer mainly involve the participation of N-H and C=O groups. DFT calculation demonstrates the uptake of Cr(III) by ester-terminated adsorbents mainly involves carbonyl oxygen and secondary amine nitrogen atoms to form tetra-coordinated chelate, while that of amino-terminated one tends to form hexa-coordinated chelates by carbonyl oxygen, primary and secondary amine nitrogen atoms.

Fabrication of dual network self-healing alginate/guar gum hydrogels based on polydopamine-type microcapsules from mesoporous silica nanoparticles.

In this manuscript, dual network self-healing alginate/guar gum hydrogels with polydopamine-type microcapsules from mesoporous silica nanoparticles were facilely prepared through one-pot method. Glutaraldehyde (GA) was used as a crosslinking agent to crosslink guar gum and sodium alginate, respectively. Metal-ligand interactions as reversible non-covalent bonds make the dual network hydrogels have a high degree of self-healing ability, which FeCl3·6H2O was coordinated with sodium alginate and polydopamine on the surface of microcapsules, respectively. The dual network structure significantly enhances the strength of the hydrogels (up to 7.3 MPa). It has also proved that these hydrogels exhibit excellent self-healing performance at ambient temperatures, which self-healing efficiency can reach to 95.5%. The obtained self-healing hydrogels have a promising application prospect for the design and synthesis of functional self-healing materials.