Ultrathin Tunable Optomechanical Metalens.

Reconfigurable metasurfaces offer great promises to enhance photonics technology by combining integration with improved functionalities. Recently, reconfigurability in otherwise static metasurfaces has been achieved by modifying the electric permittivity of the meta-atoms themselves or their immediate surrounding. Yet, it remains challenging to achieve significant and fast tunability without increasing bulkiness. Here, we demonstrate an ultrathin tunable metalens whose focal distance can be changed through optomechanical control with moderate continuous wave intensities. We achieve fast focal length changes of more than 5% with response time of the order of 10 µs.

Levitated Optomechanics with Meta-Atoms.

We propose to introduce additional control in levitated optomechanics by trapping a meta-atom, i.e., a subwavelength and high-permittivity dielectric particle supporting Mie resonances. In particular, we theoretically demonstrate that optical levitation and center-of-mass ground-state cooling of silicon nanoparticles in vacuum is not only experimentally feasible but it offers enhanced performance over widely used silica particles in terms of trap frequency, trap depth, and optomechanical coupling rates. Moreover, we show that, by adjusting the detuning of the trapping laser with respect to the particle's resonance, the sign of the polarizability becomes negative, enabling levitation in the minimum of laser intensity, e.g., at the nodes of a standing wave. The latter opens the door to trapping nanoparticles in the optical near-field combining red and blue-detuned frequencies, in analogy to two-level atoms, which is of interest for generating strong coupling to photonic nanostructures and short-distance force sensing.

Precision Calibration of the Duffing Oscillator with Phase Control.

The Duffing oscillator is a nonlinear extension of the ubiquitous harmonic oscillator and as such plays an outstanding role in science and technology. Experimentally, the system parameters are determined by a measurement of its response to an external excitation. When changing the amplitude or frequency of the external excitation, a sudden jump in the response function reveals the nonlinear dynamics prominently. However, this bistability leaves part of the full response function unobserved, which limits the precise measurement of the system parameters. Here, we exploit the often unknown fact that the response of a Duffing oscillator with nonlinear damping is a unique function of its phase. By actively stabilizing the oscillator's phase we map out the full response function. This phase control allows us to precisely determine the system parameters. Our results are particularly important for characterizing nanoscale resonators, where nonlinear effects are observed readily and which hold great promise for next generation of ultrasensitive force and mass measurements. We demonstrate our approach experimentally with an optically levitated particle in high vacuum.

Mechanical Squeezing via Unstable Dynamics in a Microcavity.

We theoretically show that strong mechanical quantum squeezing in a linear optomechanical system can be rapidly generated through the dynamical instability reached in the far red-detuned and ultrastrong coupling regime. We show that this mechanism, which harnesses unstable multimode quantum dynamics, is particularly suited to levitated optomechanics, and we argue for its feasibility for the case of a levitated nanoparticle coupled to a microcavity via coherent scattering. We predict that for submillimeter-sized cavities the particle motion, initially thermal and well above its ground state, becomes mechanically squeezed by tens of decibels on a microsecond timescale. Our results bring forth optical microcavities in the unresolved sideband regime as powerful mechanical squeezers for levitated nanoparticles, and hence as key tools for quantum-enhanced inertial and force sensing.

Applications and challenges of thermoplasmonics.

Over the past two decades, there has been a growing interest in the use of plasmonic nanoparticles as sources of heat remotely controlled by light, giving rise to the field of thermoplasmonics. The ability to release heat on the nanoscale has already impacted a broad range of research activities, from biomedicine to imaging and catalysis. Thermoplasmonics is now entering an important phase: some applications have engaged in an industrial stage, while others, originally full of promise, experience some difficulty in reaching their potential. Meanwhile, innovative fundamental areas of research are being developed. In this Review, we scrutinize the current research landscape in thermoplasmonics, with a specific focus on its applications and main challenges in many different fields of science, including nanomedicine, cell biology, photothermal and hot-electron chemistry, solar light harvesting, soft matter and nanofluidics.

Extending Vacuum Trapping to Absorbing Objects with Hybrid Paul-Optical Traps.

The levitation of condensed matter in vacuum allows the study of its physical properties under extreme isolation from the environment. It also offers a venue to investigate quantum mechanics with large systems, at the transition between the quantum and classical worlds. In this work, we study a novel hybrid levitation platform that combines a Paul trap with a weak but highly focused laser beam, a configuration that integrates a deep potential with excellent confinement and motion detection. We combine simulations and experiments to demonstrate the potential of this approach to extend vacuum trapping and interrogation to a broader range of nanomaterials, such as absorbing particles. We study the stability and dynamics of different specimens, such as fluorescent dielectric crystals and gold nanorods, and demonstrate stable trapping down to pressures of 1 mbar.

Enhanced Chiral Sensing with Dielectric Nanoresonators.

Chiro-sensitive molecular detection is highly relevant as many biochemical compounds, the building blocks of life, are chiral. Optical chirality is conventionally detected through circular dichroism (CD) in the UV range, where molecules naturally absorb. Recently, plasmonics has been proposed as a way to boost the otherwise very weak CD signal and translate it to the visible/NIR range, where technology is friendlier. Here, we explore how dielectric nanoresonators can contribute to efficiently differentiate molecular enantiomers. We study the influence of the detuning between electric (ED) and magnetic dipole (MD) resonances in silicon nanocylinders on the quality of the CD signal. While our experimental data, supported by numerical simulations, demonstrate that dielectric nanoresonators can perform even better than their plasmonic counterpart, exhibiting larger CD enhancements, we do not observe any significant influence of the optical chirality.

On-Demand Activation of Photochromic Nanoheaters for High Color Purity 3D Printing.

The creation of white and multicoloured 3D-printed objects with high color fidelity via powder sintering processes is currently limited by discolouration from thermal sensitizers used in the printing process. Here, we circumvent this problem by using switchable, photochromic tungsten oxide nanoparticles, which are colorless even at high concentrations. Upon ultraviolet illumination, the tungsten oxide nanoparticles can be reversibly activated, making them highly absorbing in the infrared. Their strong infrared absorption upon activation renders them efficient photothermal sensitizers that can act as fusing agents for polymer powders in sintering-based 3D printing. The WO3 nanoparticles show fast activation times, and when mixed with polyamide powders, they exhibit a heating-to-color-change ratio greatly exceeding other sensitizers in the literature. Upon mixing with colored inks, powders containing WO3 display identical coloration to a pristine powder. This demonstrates the potential of WO3, and photochromic nanoparticles in general as a new class of material for advanced manufacturing.

Plasmon-Based Biofilm Inhibition on Surgical Implants.

The insertion of an implant in the body of a patient raises the risk of a posterior infection and formation of a biofilm, which can have critical consequences on the patient's health and be associated with a high sanitary cost. While antibacterial agents can be used to prevent the infection, such a strategy is time-limited and causes bacteria resistance. As an alternative to biochemical approaches, we propose here to use light-induced local hyperthermia with plasmonic nanoparticles. This strategy is implemented on surgical meshes, extensively used in the context of hernia repairing, one of the most common general surgeries. Surgical meshes were homogeneously coated with gold nanorods designed to efficiently convert near-infrared light into heat. The modified mesh was exposed to a biofilm of Staphylococcus aureus ( S. aureus) bacteria before being treated with a train of light pulses. We systematically study how the illumination parameters, namely fluence, peak intensity and pulse length, influence the elimination of attached bacteria. Additionally, fluorescence confocal microscopy provides us some insight on the mechanism involved in the degradation of the biofilm. This proof-of-principle study opens a new set of opportunities for the development of novel disinfection approaches combining light and nanotechnology.

Optimal Feedback Cooling of a Charged Levitated Nanoparticle with Adaptive Control.

We use an optimal control protocol to cool one mode of the center-of-mass motion of an optically levitated nanoparticle. The feedback technique relies on exerting a Coulomb force on a charged particle with a pair of electrodes and follows the control law of a linear quadratic regulator, whose gains are optimized by a machine learning algorithm in under 5 s. With a simpler and more robust setup than optical feedback schemes, we achieve a minimum center-of-mass temperature of 5 mK at 3×10^{-7} mbar and transients 10-600 times faster than cold damping. This cooling technique can be easily extended to 3D cooling and is particularly relevant for studies demanding high repetition rates and force sensing experiments with levitated objects.

Resolved-Sideband Cooling of a Levitated Nanoparticle in the Presence of Laser Phase Noise.

We investigate the influence of laser phase noise heating on resolved sideband cooling in the context of cooling the center-of-mass motion of a levitated nanoparticle in a high-finesse cavity. Although phase noise heating is not a fundamental physical constraint, the regime where it becomes the main limitation in Levitodynamics has so far been unexplored and hence embodies from this point forward the main obstacle in reaching the motional ground state of levitated mesoscopic objects with resolved sideband cooling. We reach minimal center-of-mass temperatures comparable to T_{min}=10 mK at a pressure of p=3×10^{-7} mbar, solely limited by phase noise. Finally we present possible strategies towards motional ground state cooling in the presence of phase noise.

Enantiomer-Selective Molecular Sensing Using Racemic Nanoplasmonic Arrays.

Building blocks of life show well-defined chiral symmetry which has a direct influence on their properties and role in Nature. Chiral molecules are typically characterized by optical techniques such as circular dichroism (CD) where they exhibit signatures in the ultraviolet frequency region. Plasmonic nanostructures have the potential to enhance the sensitivity of chiral detection and translate the molecular chirality to the visible spectral range. Despite recent progress, to date, it remains unclear which properties plasmonic sensors should exhibit to maximize this effect and apply it to reliable enantiomer discrimination. Here, we bring further insight into this complex problem and present a chiral plasmonic sensor composed of a racemic mixture of gammadions with no intrinsic CD, but high optical chirality and electric field enhancements in the near-fields. Owing to its unique set of properties, this configuration enables us to directly differentiate phenylalanine enantiomers in the visible frequency range.

Motion Control and Optical Interrogation of a Levitating Single Nitrogen Vacancy in Vacuum.

Levitation optomechanics exploits the unique mechanical properties of trapped nano-objects in vacuum to address some of the limitations of clamped nanomechanical resonators. In particular, its performance is foreseen to contribute to a better understanding of quantum decoherence at the mesoscopic scale as well as to lead to novel ultrasensitive sensing schemes. While most efforts have focused so far on the optical trapping of low-absorption silica particles, further opportunities arise from levitating objects with internal degrees of freedom, such as color centers. Nevertheless, inefficient heat dissipation at low pressures poses a challenge because most nano-objects, even with low-absorption materials, experience photodamage in an optical trap. Here, by using a Paul trap, we demonstrate levitation in vacuum and center-of-mass feedback cooling of a nanodiamond hosting a single nitrogen-vacancy center. The achieved level of motion control enables us to optically interrogate and characterize the emitter response. The developed platform is applicable to a wide range of other nano-objects and represents a promising step toward coupling internal and external degrees of freedom.

White and Brightly Colored 3D Printing Based on Resonant Photothermal Sensitizers.

The use of photothermal sensitizers to facilitate the sintering of polymer powders is rapidly becoming a pivotal additive manufacturing technology, impacting multiple sectors of industry. However, conventional carbon-based sensitizers can only produce black or gray objects. To create white or colorful prints with this method, visibly transparent equivalents are needed. Here, we address this problem by designing resonant photothermal sensitizers made of plasmonic nanoparticles that strongly absorb in the near-infrared, while only minimally interacting with visible light. Gold nanorods were coated with silica before being mixed with polyamide powders to create stable colorful nanocomposite powders. At resonance, these composites showed greatly improved light-to-heat conversion compared with equivalent composites using the industry standard carbon black as a sensitizer and could be sintered using low-power light sources. Furthermore, they appear much whiter and can produce brightly colored 3D objects when mixed with dyes. Our results open a new route to utilize plasmonic nanoparticles to produce colorful and functional 3D-printed objects.

On-a-chip Biosensing Based on All-Dielectric Nanoresonators.

Nanophotonics has become a key enabling technology in biomedicine with great promises in early diagnosis and less invasive therapies. In this context, the unique capability of plasmonic noble metal nanoparticles to concentrate light on the nanometer scale has widely contributed to biosensing and enhanced spectroscopy. Recently, high-refractive index dielectric nanostructures featuring low loss resonances have been proposed as a promising alternative to nanoplasmonics, potentially offering better sensing performances along with full compatibility with the microelectronics industry. In this letter we report the first demonstration of biosensing with silicon nanoresonators integrated in state-of-the-art microfluidics. Our lab-on-a-chip platform enables detecting Prostate Specific Antigen (PSA) cancer marker in human serum with a sensitivity that meets clinical needs. These performances are directly compared with its plasmonic counterpart based on gold nanorods. Our work opens new opportunities in the development of future point-of-care devices toward a more personalized healthcare.

Plasmonic Waveguide-Integrated Nanowire Laser.

Next-generation optoelectronic devices and photonic circuitry will have to incorporate on-chip compatible nanolaser sources. Semiconductor nanowire lasers have emerged as strong candidates for integrated systems with applications ranging from ultrasensitive sensing to data communication technologies. Despite significant advances in their fundamental aspects, the integration within scalable photonic circuitry remains challenging. Here we report on the realization of hybrid photonic devices consisting of nanowire lasers integrated with wafer-scale lithographically designed V-groove plasmonic waveguides. We present experimental evidence of the lasing emission and coupling into the propagating modes of the V-grooves, enabling on-chip routing of coherent and subdiffraction confined light with room-temperature operation. Theoretical considerations suggest that the observed lasing is enabled by a waveguide hybrid photonic-plasmonic mode. This work represents a major advance toward the realization of application-oriented photonic circuits with integrated nanolaser sources.

Direct Measurement of Photon Recoil from a Levitated Nanoparticle.

The momentum transfer between a photon and an object defines a fundamental limit for the precision with which the object can be measured. If the object oscillates at a frequency Ω_{0}, this measurement backaction adds quanta ℏΩ_{0} to the oscillator's energy at a rate Γ_{recoil}, a process called photon recoil heating, and sets bounds to coherence times in cavity optomechanical systems. Here, we use an optically levitated nanoparticle in ultrahigh vacuum to directly measure Γ_{recoil}. By means of a phase-sensitive feedback scheme, we cool the harmonic motion of the nanoparticle from ambient to microkelvin temperatures and measure its reheating rate under the influence of the radiation field. The recoil heating rate is measured for different particle sizes and for different excitation powers, without the need for cavity optics or cryogenic environments. The measurements are in quantitative agreement with theoretical predictions and provide valuable guidance for the realization of quantum ground-state cooling protocols and the measurement of ultrasmall forces.

Nanoplasmonics for chemistry.

Noble metal nanoparticles supporting plasmonic resonances behave as efficient nanosources of light, heat and energetic electrons. Owing to these properties, they offer a unique playground to trigger chemical reactions on the nanoscale. In this tutorial review, we discuss how nanoplasmonics can benefit chemistry and review the most recent developments in this new and fast growing field of research.

Deterministic optical-near-field-assisted positioning of nitrogen-vacancy centers.

Nanopositioning of single quantum emitters to control their coupling to integrated photonic structures is a crucial step in the fabrication of solid-state quantum optics devices. We use the optical near-field enhancement produced by nanofabricated gold antennas subject to near-infrared illumination to deterministically trap and position single nanodiamonds (NDs) hosting nitrogen-vacancy (NV) centers. The positioning of the NDs at the antenna regions of maximum field intensity is first characterized using both fluorescence and electron microscopy imaging. We further study the interaction between the nanoantenna and the delivered NV center by analyzing its change in fluorescence lifetime, which is driven by the increase in the local density of optical states at the trapping positions. Additionally, the plasmonic enhancement of the near-field intensity allows us to optically control the NV excited lifetime using relatively low NIR illumination intensities, some 20 times lower than in the absence of the antennas.

LSPR chip for parallel, rapid, and sensitive detection of cancer markers in serum.

Label-free biosensing based on metallic nanoparticles supporting localized surface plasmon resonances (LSPR) has recently received growing interest (Anker, J. N., et al. Nat. Mater. 2008, 7, 442-453). Besides its competitive sensitivity (Yonzon, C. R., et al. J. Am. Chem. Soc. 2004, 126, 12669-12676; Svendendahl, M., et al. Nano Lett. 2009, 9, 4428-4433) when compared to the surface plasmon resonance (SPR) approach based on extended metal films, LSPR biosensing features a high-end miniaturization potential and a significant reduction of the interrogation device bulkiness, positioning itself as a promising candidate for point-of-care diagnostic and field applications. Here, we present the first, paralleled LSPR lab-on-a-chip realization that goes well beyond the state-of-the-art, by uniting the latest advances in plasmonics, nanofabrication, microfluidics, and surface chemistry. Our system offers parallel, real-time inspection of 32 sensing sites distributed across 8 independent microfluidic channels with very high reproducibility/repeatability. This enables us to test various sensing strategies for the detection of biomolecules. In particular we demonstrate the fast detection of relevant cancer biomarkers (human alpha-feto-protein and prostate specific antigen) down to concentrations of 500 pg/mL in a complex matrix consisting of 50% human serum.