Controlling water giant low-inertia nonlinear refractive index in the THz frequency range via temperature variation.

To create self-controlled radiation photonics systems, it is necessary to have complete information about the nonlinear properties of the materials used. In this Letter, the vibrational mechanism of the giant low-inertia cubic nonlinearity of the refractive index of water in the terahertz (THz) frequency range is experimentally proven. Its dominance, which manifests itself when the temperature of the liquid changes, is demonstrated. The measured nonlinear refractive index in the THz frequency range for a water jet at temperatures from 14°C to 21°C demonstrates a correlation with the theoretical approach, varies in the range 4-10 × 10-10 cm2/W, and is characterized by an inertial time constant of less than 1 ps.

Hyperspectral data denoising for terahertz pulse time-domain holography.

We investigated data denoising in hyperspectral terahertz pulse time-domain holography. Using the block-matching algorithms adapted for spatio-temporal and spatio-spectral volumetric data we studied and optimized parameters of these algorithms to improve phase image reconstruction quality. We propose a sequential application of the two algorithms oriented on work in temporal and spectral domains. Experimental data demonstrate the improvement in the quality of the resultant time-domain images as well as phase images and object's relief. The simulation results are proved by comparison with the experimental ones.

Direct measurement of the parameters of a femtosecond pulse train with a THz repetition rate generated by the interference of two phase-modulated femtosecond pulses.

A femtosecond pulse train with THz repetition rate generated by the interference of two phase-modulated pulses has been recorded experimentally. Pulse repetition rates and their duration have been measured. It has been shown that at the 50-fs time delay between phase-modulated pulses the repetition rate is 3.1 THz with a pulse width of 200 fs, while at the 120-fs time delay the repetition rate is 7.1 THz with a pulse width of 67 fs.

Revealing the nature of optical activity in carbon dots produced from different chiral precursor molecules.

Carbon dots (CDs) are light-emitting nanoparticles that show great promise for applications in biology and medicine due to the ease of fabrication, biocompatibility, and attractive optical properties. Optical chirality, on the other hand, is an intrinsic feature inherent in many objects in nature, and it can play an important role in the formation of artificial complexes based on CDs that are implemented for enantiomer recognition, site-specific bonding, etc. We employed a one-step hydrothermal synthesis to produce chiral CDs from the commonly used precursors citric acid and ethylenediamine together with a set of different chiral precursors, namely, L-isomers of cysteine, glutathione, phenylglycine, and tryptophan. The resulting CDs consisted of O,N-doped (and also S-doped, in some cases) carbonized cores with surfaces rich in amide and hydroxyl groups; they exhibited high photoluminescence quantum yields reaching 57%, chiral optical signals in the UV and visible spectral regions, and two-photon absorption. Chiral signals of CDs were rather complex and originated from a combination of the chiral precursors attached to the CD surface, hybridization of lower-energy levels of chiral chromophores formed within CDs, and intrinsic chirality of the CD cores. Using DFT analysis, we showed how incorporation of the chiral precursors at the optical centers induced a strong response in their circular dichroism spectra. The optical characteristics of these CDs, which can easily be dispersed in solvents of different polarities, remained stable during pH changes in the environment and after UV exposure for more than 400 min, which opens a wide range of bio-applications.

Photoluminescence quenching of dye molecules near a resonant silicon nanoparticle.

Luminescent molecules attached to resonant colloidal particles are an important tool to study light-matter interaction. A traditional approach to enhance the photoluminescence intensity of the luminescent molecules in such conjugates is to incorporate spacer-coated plasmonic nanoantennas, where the spacer prevents intense non-radiative decay of the luminescent molecules. Here, we explore the capabilities of an alternative platform for photoluminescence enhancement, which is based on low-loss Mie-resonant colloidal silicon particles. We demonstrate that resonant silicon particles of spherical shape are more efficient for photoluminescence enhancement than their plasmonic counterparts in spacer-free configuration. Our theoretical calculations show that significant enhancement originates from larger quantum yields supported by silicon particles and their resonant features. Our results prove the potential of high-index dielectric particles for spacer-free enhancement of photoluminescence, which potentially could be a future platform for bioimaging and nanolasers.