Recent advancements in the field of flexible/wearable enzyme fuel cells.

This review article focusses on new advances in the field of enzyme fuel cells (EFCs), especially, on flexible materials which can be used to make flexible EFCs for wearable devices, three-dimensional (3D) printed structures to prepare electrodes for EFCs and micro/nano electromechanical structures (MEMS/NEMS) to fabricate micro-EFCs. Particular attention is given to newly developed approaches to obtain efficient electrodes for harvesting energy via EFCs. This review article explains the various attributes of these recently developing technologies and their ability to mitigate the energy requirements of flexible/wearable bioelectronic devices. Besides discussing key milestones achieved, this perspective review article also emphasizes the main hurdles that are currently impeding the realization of flexible/wearable EFCs. We have also emphasized on the major hurdles related to the flexible materials required to fabricate wearable EFCs, suitable 3D printing techniques required, and MEMS and NEMS to fabricate micro-EFCs. In all the recently developed techniques, there are some common issues like stability, low power output, mechanical strength and flexibility. This review article also provides various routes to mitigate these issues. The main aim of this perspective article is to develop curiosity among the researchers of various fields to team up in order to address the huge challenges that restrict the real-world application of flexible/wearable EFCs. Such collaboration is important to harness the full potential of EFCs. It is requested to read this review article with supporting information to get the complete essence.

Electrocatalytic Performance of Chemically Synthesized PIn-Au-SGO Composite toward Mediated Biofuel Cell Anode.

The proposed work intended to make an intellectual contribution to the domain of green nanotechnology which emphasizes the chemical synthesis of a conducting nanocomposite based on the incorporation of gold nanoparticles (Au) into the redox matrix of polyindole (PIn) along with the subsequent improvement in the overall properties of the composite by the addition of sulfonated graphene oxide (SGO). The bioanode was developed by the deposition of the PIn-Au-SGO nanocomposite with subsequent immobilization of ferritin (Frt) and glucose oxidase (GOx) on the glassy carbon electrode (GC). The successful application of the PIn-Au-SGO nanocomposite toward the development of a ferritin-mediated glucose biofuel cell anode was studied by the electrochemical characterization of the constructed bioanode (GC-PIn-Au-SGO/Frt/GOx) for the bioelectrocatalytic oxidation of glucose. The maximum current density obtained by the modified bioanode was found to be 17.8 mA cm-2 at the limiting glucose concentration of 50 mM in 0.1 M K4Fe(CN)6 at a scan rate of 100 mVs-1. The lifetime of the concerned bioelectrode when stored at 4 °C was estimated to be 53 days approximately. The appreciable results of the structural and electrochemical characterization of the PIn-Au-SGO based bioelectrode reveal its potential applications exclusively in implantable medical devices.