Electricity-Driven Strategies for Bioinspired Multifunctional Swimming Marangoni Robots Based on Super-Aligned Carbon Nanotube Composites.

Marangoni actuators that are propelled by surface tension gradients hold significant potential in small-scale swimming robots. Nevertheless, the release of "fuel" for conventional chemical Marangoni actuators is not easily controllable, and the single swimming function also limits application areas. Constructing controllable Marangoni robots with multifunctions is still a huge challenge. Herein, inspired by water striders, electricity-driven strategies are proposed for a multifunctional swimming Marangoni robot (MSMR), which is fabricated by super-aligned carbon nanotube (SACNT) and polyimide (PI) composite. The MSMR consists of a Marangoni actuator and air-ambient actuators. Owing to the temperature gradient generated by the electrical stimulation on the water surface, the Marangoni actuators can swim controllably with linear, turning, and rotary motions, mimicking the walking motion of water striders. In addition, the Marangoni actuators can also be driven by light. Importantly, the air-ambient actuators fabricated by SACNT/PI bilayer structures demonstrate the function of grasping objects on the water surface when electrically Joule-heated, mimicking the predation behavior of water striders. With the synergistic effect of the Marangoni actuator and air-ambient actuators, the MSMR can navigate mazes with tunnels and grasp objects. This research will provide a new inspiration for smart actuators and swimming robots.

Soft multi-layer actuators integrated with the functions of electrical energy harvest and storage.

Soft multi-layer actuators are smart, lightweight, and flexible, which can be used in a wide range of fields such as artificial muscles, advanced medical devices, and wearable devices. The research on the actuation property of the soft actuators has made significant progress, paving the way for the controllable motions of the actuators. However, compared with the intelligence and adaptability of life in nature, these actuators still have the problem of insufficient intelligence. The phenomenon is reflected in a lack of continuous supply of energy. Therefore, it has become a development trend to combine functions such as energy harvesting, storage, and conversion with actuators to build intelligent actuators. This concept presents a synopsis of the advancements made in soft actuators that have been coupled with the capabilities of electrical energy harvesting and storage. The design concepts and typical applications of this soft smart actuators are introduced in detail. Finally, the future research directions and applications of smart actuators are prospected from our perspective.

Multi-Functional Actuators Made with Biomass-Based Graphene-Polymer Films for Intelligent Gesture Recognition and Multi-Mode Self-Powered Sensing.

Multi-functional actuation systems involve the mechanical integration of multiple actuation and sensor devices with external energy sources. The intricate combination makes it difficult to meet the requirements of lightweight. Hence, polypyrrole@graphene-bacterial cellulose (PPy@G-BC) films are proposed to construct multi-responsive and bilayer actuators integrated with multi-mode self-powered sensing function. The PPy@G-BC film not only exhibits good photo-thermoelectric (PTE) properties but also possesses good hydrophilicity and high Young's modulus. Thus, the PPy@G-BC films are used as active layers in multi-responsive bilayer actuators integrated with self-powered sensing functions. Here, two types of multi-functional actuators integrated with self-powered sensing functions is designed. One is a light-driven actuator that realizes the self-powered temperature sensing function through the PTE effect. Assisted by a machine learning algorithm, the self-powered bionic hand can realize intelligent gesture recognition with an accuracy rate of 96.8%. The other is humidity-driven actuators integrated a zinc-air battery, which can realize self-powered humidity sensing. Based on the above advantages, these two multi-functional actuators are ingeniously integrated into a single device, which can simultaneously perform self-powered temperature/humidity sensing while grasping objects. The highly integrated design enables the efficient utilization of environmental energy sources and complementary synergistic monitoring of multiple physical properties without increasing system complexity.

Pencil-Drawn Generator Built-in Actuator for Integrated Self-Powered/Visual Dual-Mode Sensing Functions and Rewritable Display.

Multifunctionality is important to the development of next-generation actuators and intelligent robots. However, current multi-functional actuating systems are achieved based on the integration of diverse functional units with complex design, especially lacking in multi-mode sensing and displaying functions. Herein, a light-driven actuator integrated with self-powered/visual dual-mode sensing functions and rewritable display function is proposed. The actuator demonstrates a bending curvature of 0.93 cm-1 under near-infrared light irradiation. Meanwhile, by embedding a pencil-drawn graphite generator and thermochromic materials, the actuator also provides two independent sensing functions. First, owing to the photo-thermoelectric effect of graphite, the actuator spontaneously outputs a self-powered voltage (Seebeck coefficient: 23 µV K-1 ), which can reflect the deformation trend of actuator. Second, color changes occur on the actuator during deformation, which provide a visual sensing due to the thermochromic property. Furthermore, the actuator can be utilized as a rewritable display, owing to the integrated color-memorizing component. Intelligent robots, switches, and smart homes are further demonstrated as applications. All of them can spontaneously provide self-powered and visual sensing signals to demonstrate the working states of actuating systems, accompanied by rewritable displays on the actuators. This study will open a new direction for self-powered devices, multi-functional actuators, and intelligent robots.

A PEDOT:PSS/MXene-based actuator with self-powered sensing function by incorporating a photo-thermoelectric generator.

Actuators with sensing functions are becoming increasingly important in the field of soft robotics. However, most of the actuators are lack of self-powered sensing ability, which limits their applications. Here, we report a light-driven actuator with self-powered sensing function, which is designed to incorporate a photo-thermoelectric generator into the actuator based on poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)/MXene composite and polyimide. The actuator shows a large bending curvature of 1.8 cm-1 under near-infrared light (800 mW cm-2) irradiation for 10 s, which is attribute to photothermal expansion mismatch between PEDOT:PSS/MXene composite and polyimide. Simultaneously, the actuator shows enhanced thermoelectric properties with Seebeck coefficient of 35.7 µV K-1, which are mainly attributed to a combination of energy filtering effects between the PEDOT:PSS and MXene interfaces as well as the synergistic effect of its charge carrier migration. The output voltage of the actuator changes in accordance with the bending curvature, so as to achieve the self-powered sensing function and monitor the operating state of the actuator. Moreover, a bionic flower is fabricated, which not only simulates the blooming and closing of the flower, but also perceives the real-time actuation status through the output voltage signal. Finally, a smart Braille system is elaborately designed, which can not only simulate Braille characters for tactile recognition of the blind people, but also automatically output the voltage signal of Braille for self-powered sensing, enabling multi-channel output and conversion of light energy. This research proposes a new idea for exploring multifunctional actuators, integrated devices and self-powered soft robots.

Self-chargeable supercapacitor made with MXene-bacterial cellulose nanofiber composite for wearable devices.

The development of wearable electronics is restricted by the developments of supporting energy storage devices, especially flexible supercapacitors. Nowadays, miniaturized supercapacitors based on MXenes due to their obvious advantages in the specific capacity have received extensive attention. The energy existing in the surrounding environment has been used to directly charge energy storage devices. However, the hybrid wearable electronics integrated supercapacitors are mechanically connected through metal wires leading to non-compact devices. Thus, it is urgent to develop a general and universal method to fabricate high-performance robust MXene-based flexible electrodes with high electrical conductivity and apply them to self-chargeable supercapacitors and compact wearable devices. Herein, the bacterial cellulose (BC) nanofibers are used as a crosslinking agent to connect two-dimensional MXene nanosheets through the hydrogen bond, which greatly improves the mechanical strength of MXene-bacterial cellulose (MXene-BC) composite films (Young's modulus reaching 6.8 GPa). The supercapacitors made with the electrodes of MXene-BC composite films (BC content is 10%) present high capacitance behavior (areal capacitance up to 346 mF cm-2) because the introduction of BC nanofibers increases the interlayer spacing of MXene nanosheets, providing more storage space for the ions in the electrolyte. Then, a self-chargeable supercapacitor is proposed based on the combination of a zinc-air (Zn-air) battery and a supercapacitor. The self-chargeable supercapacitor can realize self-charging after dropping a drop of electrolyte solution into the Zn-air battery. The charging voltage of a single self-chargeable supercapacitor can reach 0.6 V after adding artificial sweat as the electrolyte. Finally, a smart wristband with the function of self-charging is proposed, which can absorb the sweat generated by the human for self-chargeable supercapacitors to drive the pedometer integrated within the smart wristband to work. The proposed self-chargeable supercapacitors are simple and effective, not restricted by the use environment, providing a promising way for self-powered wearable electronics.

Multifunctional actuators integrated with the function of self-powered temperature sensing made with Ti3C2Tx-bamboo nanofiber composites.

In recent years, multifunctional actuators have received increasing attention and development. In particular, researchers have conducted extensive research on intelligent actuators with integrated sensing functions. Temperature is an important parameter for the deformation of bilayer thermal actuators. By obtaining the temperature information of a bilayer thermal actuator, the deformation amplitude and its state can be judged. Thus, there is an urgent need to develop a type of intelligent actuator with a self-powered temperature sensing function. Herein, Ti3C2Tx-based composites modified with bamboo nanofibers have been proposed and applied to intelligent actuators integrated with a self-powered temperature sensing function. By utilizing the coefficients of thermal expansion between Ti3C2Tx-bamboo nanofiber composites and a polyimide film, a bilayer photo/electro-driven thermal actuator is designed which shows a bending curvature as large as 1.9 cm-1. In addition, Ti3C2Tx-bamboo nanofiber composites have a Seebeck coefficient of -9.15 µV K-1, and are N-type thermoelectric materials and can be used as the component of self-powered temperature sensors. Finally, a series of practical applications were designed, including a light-driven floating actuator (with a moving speed of 5 mm s-1), biomimetic sunflowers, bionic tentacles, and a multifunctional gripper integrated with a self-powered temperature sensing function. In particular, the multifunctional grippers can output voltage signals carrying their temperature information without external complex power sources, demonstrating their potential for remote monitoring. The above results demonstrate that Ti3C2Tx-bamboo nanofiber composites have extensive practical applications in fields such as self-powered sensors, flexible thermoelectric generators, and soft actuators.

Pressure-Perceptive Actuators for Tactile Soft Robots and Visual Logic Devices.

Soft actuators with sensing capabilities are important in intelligent robots and human-computer interactions. However, present perceptive actuating systems rely on the integration of multiple functional units with complex circuit design. Here, a new-type pressure-perceptive actuator is reported, which integrates functions of sensing, actuating, and decision making at material level without complex combination. The actuator is composed of an actuating unit and a pressure-sensing unit, both of which are fabricated by carbon nanotube (CNT), silk, and polymer composite. On the one hand, the actuating unit can be driven by low voltages (<13 V), owing to a Joule-heating effect. On the other hand, the current passing the pressure-sensing unit can be controlled by tactile pressure. In the integrated actuator, it is able to control the deformation amplitude of actuating unit by applying different pressures on the pressure-sensing unit. A portable tactile-activated gripper is fabricated to operate an object through pressure control, demonstrating its application in tactile soft robots. Finally, three visual logic gates (AND, OR, and NOT) are proposed, which convert "tactile" inputs into "visible" deformation outputs, using the CNT-silk-based material for sensing and actuating in the decision-making process. This study provides a new path for intelligent soft robots and new-generation logic devices.

Chinese ink: a programmable, dual-responsive and self-sensing actuator using a healing-assembling method.

Actuators have wide applications in soft robotics and bionic devices. Since the healing ability not only makes actuators have longer service lives, but also allows them to be programmable through welding and assembling, it is regarded as an important feature for state-of-the-art actuators. Nevertheless, it remains a great challenge to integrate multi-functional merits, such as multi-responsiveness, programmable shape-morphing, healing and self-sensing function, simultaneously into a monolithic actuating material. Here, we introduce Chinese ink, a carbon-based material used in traditional calligraphy, to develop programmable, dual-responsive and self-sensing actuators by a healing-assembling method. The ink is combined with graphene oxide (GO) to fabricate a double-layer ink/GO actuator, which shows bi-directional bending under near-infrared light or humidity, owing to the mismatch of the volume change between ink and GO films. The maximal bending curvature is up to 5.2 cm-1. Importantly, the entire ink/GO actuator can be healed with the aid of ink solution. Using the healing-assembling method to fabricate advanced structures including a Mobius ring, triangular rings and square rings, diverse actuating modes and complex 3D deformations such as a wavy shape and saddle shape are realized. This method also enables the construction of an artificial mimosa that shows a biomimetic stimulus-responsive behavior. In addition, the ink/GO actuator shows a self-sensing function, which is attributed to the thermoresistivity of the ink film. This research shows the huge potential of Chinese-ink-based actuators for use in smart materials, providing a new idea for the development of new generation multi-functional actuators.

A multi-functional light-driven actuator with an integrated temperature-sensing function based on a carbon nanotube composite.

Actuators play an important role in the fields of intelligent robots and wearable electronics. Temperature has a great impact on the performances of many actuators. However, most of the traditional actuators only have an actuating function, failing to monitor and send real-time feedback of the temperature of the actuator. To solve the existing problem and break the single-function limit of traditional actuators, we propose a multi-functional light-driven actuator integrated with a temperature-sensing function, which is based on a carbon nanotube (CNT) and methylcellulose (MC) composite. When the CNT-MC film is assembled with biaxially oriented polypropylene (BOPP) to form a bilayer structure, the CNT-MC/BOPP actuator can be driven by near-infrared (NIR) light. Its morphing is based on thermal expansion differences between two layers and shrinkage of MC induced by water loss. The maximal bending curvature is up to 1.03 cm-1. Meanwhile, the resistance of the actuator can change by about 10%, which realizes real-time temperature monitoring and feedback. Furthermore, we demonstrate two practical applications. First, the CNT-MC film can work as a temperature sensor, as its resistance changes with the temperature in real time. Second, we design an intelligent gripper, which can monitor the temperature during the entire working process. This multi-functional CNT-based device is expected to have a broad application prospect in artificial muscles, soft robotics and wearable electronics.

Programmable and Self-Healing Light-Driven Actuators through Synergetic Use of Water-Shaping and -Welding Methods.

Shape programming is critical for the fabrication of a light-driven actuator with complex shape morphing, which demonstrates potential applications in remote-controlled light-driven soft robots. However, it remains a huge challenge to obtain light-driven actuators having advantages of complex shape morphing, self-healing function, and facile fabrication simultaneously. Here, we report a facile strategy to obtain programmable and self-healing light-driven actuators with complex shape morphing. Various initial shapes of actuators can be programmed by synergetic use of water-shaping and -welding methods, which provides unlimited opportunities for fabricating actuators with predesigned shapes and subsequently demonstrating complex shape morphing. A template transfer method is used to prepare a single-layer graphene oxide (GO) film with asymmetric surface structures, which acts as the basic actuator and has the self-healing function based on the hydrophilic property of GO. It shows bending morphing under near-infrared (NIR) light irradiation due to the photothermal effect and asymmetric morphology on the opposite surfaces. Four more types of actuators are programmed from the basic actuator through the water-shaping method, which exhibits bending, unbending, twisting, and untwisting, respectively, under NIR light illumination. In addition, an S-shape actuator and a flower-shape actuator are programmed from the basic actuators through the water-welding method. By simply turning over the S-shape actuator, it can perform a bidirectional crawling motion. Finally, two intricate bionic light-driven actuators (tendril-shape and octopus-shape) are constructed, which are unattainable from conventional fabrication methods of actuators. We believe that this study will unlock a new way to programmable, self-healing, and light-driven soft robots with tunable and complex shape morphing.

Humidity- and light-driven actuators based on carbon nanotube-coated paper and polymer composite.

Multi-responsive actuators driven by different stimuli (e.g. light, humidity, electricity) have attracted intense attention recently for the advantages of being used in various environments and show enormous actuation. In this work, we propose humidity- and light-driven actuators based on carbon nanotube (CNT)-coated paper and a biaxially oriented polypropylene (BOPP) composite. The CNT-paper/BOPP actuator shows large bending actuation when driven by humidity change (curvature of 1.2 cm-1) and near infrared (NIR) light irradiation (curvature up to 1.6 cm-1). The great actuation performances outperform most other paper-based actuators. Finally, a smart gripper, of which the initial opening width can be enlarged, is fabricated on the basis of the CNT-paper/BOPP actuators. By utilizing the bidirectional bending motion of the actuator, the opening width of the gripper can increase to a width that is 4 times larger than its initial width, so as to grasp a large object. The gripper is also able to raise and move an object that is 20 times heavier than one actuator of the gripper. We assume that this new type of actuator has great potential in artificial muscle, soft robotics and biomimetic applications.

Multi-responsive actuators based on a graphene oxide composite: intelligent robot and bioinspired applications.

Carbon-based electrothermal or photothermal actuators have attracted intense attention recently. They can directly convert electrical or light energy into thermal energy and exhibit obvious deformations. However, if the actuation mechanism is only limited to thermal expansion, the deformation amplitude is difficult to increase further. Moreover, complex shape-deformation is still challenging. Although a few materials were reported to realize twisting or untwisting actuation by cutting the samples into strips along different orientations, each single strip could perform only one shape-deformation mode. In this work, we propose multi-responsive actuators based on a graphene oxide (GO) and biaxially oriented polypropylene (BOPP) composite, which are designed with different shapes (strip-shape and helical-shape). The strip-shape GO/BOPP actuator shows great bending actuations when driven by humidity (curvature of up to 3.1 cm-1). Due to a developed dual-mode actuation mechanism, the actuator shows a bending curvature of 2.8 cm-1 when driven by near infrared (NIR) light. The great actuation outperforms most other carbon-based actuators. Then, an intelligent robot based on the GO/BOPP composite is fabricated, which can switch between the protection mode and weightlifting mode with different external stimuli. Inspired from plant tendrils, a bioinspired helical GO/BOPP actuator is further realized to show both twisting and untwisting actuations in a single actuator, fully mimicking the deformation of plant tendrils. Finally, a robot arm consisting of strip-shape and helical GO/BOPP actuators can grasp an object that is 2.9 times heavier than itself, demonstrating promising bioinspired applications.