Spatiotemporal Changes of Antibiotic Resistance, Potential Pathogens, and Health Risk in Kindergarten Dust.

The microorganisms present in kindergartens are extremely important for children's health during their three-year preschool education. To assess the risk of outdoor dust in kindergartens, the antibiotic resistome and potential pathogens were investigated in dust samples collected from 59 kindergartens in Xiamen, southeast China in both the winter and summer. Both high-throughput quantitative PCR and metagenome analysis revealed a higher richness and abundance of antibiotic resistance genes (ARGs) in winter (P < 0.05). Besides, the bloom of ARGs and potential pathogens was evident in the urban kindergartens. The co-occurrence patterns among ARGs, mobile genetic elements (MGEs), and potential pathogens suggested some bacterial pathogens were potential hosts of ARGs and MGEs. We found a large number of high-risk ARGs in the dust; the richness and abundance of high-risk ARGs were higher in winter and urban kindergartens compared to in summer and peri-urban kindergartens, respectively. The results of the co-occurrence patterns and high-risk ARGs jointly reveal that urbanization will significantly increase the threat of urban dust to human beings and their risks will be higher in winter. This study unveils the close association between ARGs/mobile ARGs and potential pathogens and emphasizes that we should pay more attention to the health risks induced by their combination.

Distribution characteristics, source attribution, and health risk assessment of organophosphate esters in indoor and outdoor dust from various microenvironments in Beijing.

The occurrence and profiles of organophosphate esters (OPEs) were studied in indoor and outdoor dusts from various microenvironments, including forty-seven outdoor dusts from green belts, roads, parks and residence areas, seventy-seven indoor dusts from private cars, print shops, taxis, furniture shops, offices, dormitories, shopping malls and residences house in different districts in Beijing. The total concentrations (Σ12OPEs) were eighteen times higher in indoor dusts (7.14 ×102 to 2.24 ×104 ng/g) than in outdoor dusts (36.0-1.56 ×103 ng/g). OPEs concentrations in samples from taxi and private cars were obviously higher than other indoor microenvironments. Both indoor and outdoor microenvironments also showed different compositional profiles of OPEs, indicating that polyurethane foam/building materials and hydraulic fluids/plastics were the greatest contributions in different microenvironments, with chlorinated alkyl phosphates (Cl-OPEs) being the predominant compound in both indoor dust (52.1-86.5%) and outdoor dust samples (42.6-81.3%). The uncertainty was reduced by Monte Carlo simulation, and the pollution levels of 50th and 95th percentiles were employed to calculate the average daily dosage, which was then used to calculate hazard quotient (HQ) for assessing the health risks to adults and children. Results showed that OPEs were safe even at extremely consumed concentration percentile (95th) in all groups.

Per- and Polyfluoroalkyl Substances in Outdoor and Indoor Dust from Mainland China: Contributions of Unknown Precursors and Implications for Human Exposure.

Per- and polyfluoroalkyl substances (PFASs) were analyzed in outdoor (n = 101) and indoor dust (n = 43, 38 paired with outdoors) samples across mainland China. From 2013 to 2017, the median concentration of ∑PFASs in outdoor dust tripled from 63 to 164 ng/g with an elevated contribution of trifluoroacetic acid and 6:2 fluorotelomer alcohol. In 2017, the indoor dust levels of ∑PFASs were in the range 185-913 ng/g, which were generally higher than the outdoor dust levels (105-321 ng/g). Emerging PFASs were found at high median levels of 5.7-97 ng/g in both indoor and outdoor dust samples. As first revealed by the total oxidized precursors assay, unknown perfluoroalkyl acid (PFAA)-precursors contributed 37-67 mol % to the PFAS profiles in indoor dust samples. A great proportion of C8 PFAA-precursors were precursors for perfluorooctanesulfonic acid, while C6 and C4 PFAA-precursors were mostly fluorotelomer based. Furthermore, daily perfluorooctanoic acid (PFOA) equivalent intakes of PFAAs (C4-C12) mixtures via indoor dust were first estimated at 1.3-1.5 ng/kg b.w./d for toddlers at high scenarios, which exceeds the derived daily threshold of 0.63 ng/kg b.w./d. from the European Food Safety Authority (EFSA). On this basis, an underestimation of 56%-69% likely remains without considering potential risks due to the biotransformation of unknown PFAA-precursors.

The exposure of children to PM2.5 and dust in indoor and outdoor school classrooms in Kuala Lumpur City Centre.

It is important to assess indoor air quality in school classrooms where the air quality may significantly influence school children's health and performance. This study aims to determine the concentrations of PM2.5 and dust chemical compositions in indoor and outdoor school classroom located in Kuala Lumpur City Centre. The PM2.5 concentration was measured from 19th September 2017-16th February 2018 using an optical PM2.5 sensor. Indoor and outdoor dust was also collected from the school classrooms and ion and trace metal concentrations were analysed using ion chromatography (IC) and inductively couple plasma-mass spectrometry (ICP-MS) respectively. This study showed that the average indoor and outdoor 24 h PM2.5 was 11.2 ±â€¯0.45 µg m-3 and 11.4 ±â€¯0.44 µg m-3 respectively. The 8 h PM2.5 concentration ranged between 3.2 and 28 µg m-3 for indoor and 3.2 and 19 µg m-3 for outdoor classrooms. The highest ion concentration in indoor dust was Ca2+ with an average concentration of 38.5 ±â€¯35.0 µg g-1 while for outdoor dust SO42- recorded the highest ion concentration with an average concentration of 30.6 ±â€¯9.37 µg g-1. Dominant trace metals in both indoor and outdoor dust were Al, Fe and Zn. Principle component analysis-multiple linear regression (PCA-MLR) demonstrated that the major source of indoor dust was road dust (69%), while soil dominated the outdoor dust (74%). Health risk assessment showed that the hazard quotient (HQ) value for non-carcinogenic trace metals was < 1 while the total cancer risk (CR) value for carcinogenic elements was below the acceptable limit for both indoor and outdoor dust through dermal and inhalation pathways, but not the ingestion pathway. This study suggests indoor contributions of PM2.5 concentrations are due to the activities of the school children while the compositions of indoor and outdoor dust are greatly influenced by the soil/earth source plus industrial and traffic contribution.

Sources of halogenated brominated retardants in house dust in an industrial city in southern China and associated human exposure.

Halogenated flame retardants (HFRs) are a class of ubiquitous pollutants in the environment and attract increasing attention. In the present study, HFR concentrations were measured in indoor and outdoor dust in an important industrial city (Dongguan) in southern China, in which their presence and associated human exposure are unknown. The HFRs were dominated by polybrominated diphenyl ethers (PBDEs) and decabromodiphenyl ethane (DBDPE), with mean concentrations of 2365 and 2441 ng/g in the indoor dust, respectively, which were 2-3 order of magnitude higher the concentrations of other HFRs. However elevated tri- to hepta-BDE concentrations (869 ng/g) were found in Houjie Town, a furniture manufacturing center. The mean indoor/outdoor (I/O) ratios of HFR concentrations in the dust were all larger than one (1.55-16.4), suggesting the importance of indoors sources for HFRs in indoor dust in this industrial city. Principal component analysis (PCA) showed that the correlations among the HFRs in the indoor dust probably revealed differences in their commercial applications, while most HFRs in the outdoor dust have similar sources except for phased-out BDE47 and 99. The compositions of lower brominated PBDEs varied among the towns, probably due to their different sources or influence of photo-degradation. Nevertheless, the similar composition of highly brominated congeners indicated little photo-degradation encountered in the ambient environment. The non-cancer risk associated with indoor dust ingestion is low for the general population in Dongguan, but some children in the furniture manufacturing center have significantly high risk of exposure to banned PBDEs.

A combined toxicological impact on Artemia salina caused by the presence of dust particles, microplastics from cosmetics, and paracetamol.

Environmental pollution poses a significant and pressing threat to the overall well-being of aquatic ecosystems in modern society. This study showed that pollutants like dusts from AC filter, fan wings and Traffic dust PM 2.5 were exposed to Artemia salina in pristine form and in combination. The findings indicated that exposure to multi-pollutants had a detrimental effect on the hatching rates of A. salina cysts. Compared to untreated A. salina, the morphology of adult (7th day old) A. salina changed noticeably after each incubation period (24-120 h). Oxidative stress increased considerably as the exposure duration increased from 24 to 120 h compared to the control group. There was a time-dependent decline in antioxidant enzyme activity and total protein concentration. When all particles were used all together, the total protein content in A. salina decreased significantly. All particles showed a considerable decline in survival rate. Those exposed to traffic dust particles showed significantly higher levels of oxidative stress and antioxidant activity than those exposed to other particles.

Evidence of large-scale deposition of airborne emissions of per- and polyfluoroalkyl substances (PFASs) near a fluoropolymer production plant in an urban area.

Airborne emissions of per- and polyfluoroalkyl substances (PFASs) from fluoropolymer manufacturing facilities-especially those producing polyvinylidene (PVDF)-have rarely been investigated. Once PFASs are released into the air from the facility stacks, they settle in the surrounding environment, contaminating all surfaces. Human beings living in close proximity to these facilities can be exposed through air inhalation and ingestion of contaminated vegetables, drinking water or dust. In this study, we collected nine surface soil and five outdoor settled dust samples within 200 m of the fence line of a PVDF and fluoroelastomer production site near Lyon (France). Samples were collected in an urban area including a sports field. High concentrations of long-chain perfluoroalkyl carboxylic acids (PFCAs) (C ≥ 9) were found at sampling points downwind of the facility. Perfluoroundecanoic acid (PFUnDA) was the predominant PFAS in surface soil (12-245 ng/g dw), whereas perfluorotridecanoic acid (PFTrDA) was in outdoor dust (<0.5-59 ng/g dw). The PFAS profiles observed in soil and dust samples very likely originate from the processing aids used for PVDF and fluoroelastomer production. To our knowledge, long-chain PFCA concentrations as high as reported herein have never been found outside the perimeter fencing of a fluoropolymer plant. PFAS concentrations in other environmental compartments (such as air, vegetables or groundwater) should be monitored to assess all potential pathways to exposure of nearby residents before carrying out human biomonitoring.

Toward an interdisciplinary approach to assess the adverse health effects of dust-containing polycyclic aromatic hydrocarbons (PAHs) and metal(loid)s on preschool children.

Settled dust can function as a pollutant sink for compounds, such as polycyclic aromatic hydrocarbons (PAHs) and metal(loid)s (MMs), which may lead to health issues. Thus, dust represents a hazard specifically for young children, because of their vulnerability and hand-to-mouth behavior favoring dust ingestion. The aim of the present study was to explore the influence of the season and the microenvironment on the concentrations of 15 PAHs and 17 MMs in indoor and outdoor settled dust in three preschools (suburban, urban, and industrial). Second, the potential sources and health risks among children associated with dust PAHs and MMs were assessed. Third, domestic factors (risk perception, knowledge and parental style) were described to explore protective parental behaviors toward dust hazards. The suburban preschool had the lowest concentrations of dust PAHs and MMs, while the industrial and urban preschools had higher but similar concentrations. Seasonal tendencies were not clearly observed. Indoor dusts reflected the outdoor environment, even if specific indoor sources were noted. Source analysis indicated mainly vehicular emissions, material release, and pyrogenic or industrial sources. The non-cancer health risks were non-existent, but potential cancer health risks (between 1.10-6 and 1.10-4) occurred at all sampling locations. Notably, the highest cancer risk was observed in a playground area (>1.10-4) and material release should be further addressed. Whereas we assessed higher risk indoors, parents perceived a higher risk in the open-air environment and at the preschool than at home. They also perceived a lower risk for their own children, revealing an optimism bias, which reduces parental anxiety.

Heavy metal analysis in of indoor and outdoor dust extracts and cytotoxicity evaluation and inflammation factors on lung, gastric and skin cell lines.

Dust particles (DPs) are one of the most important public health concerns in the urban environment. The presence of heavy metals (HMs) on the surface of DPs might increase the health risk of exposure to the DPs. Accordingly, The purpose of this study was to examine the content of HMs in the outdoor and indoor DPs in Neyshabur city and assess the cytotoxic effects of DPs exposure on lung, gastric, and skin cell lines. To this end, the city was divided into three areas, high-traffic, medium-traffic, and low-traffic (rural). The average concentration of the HMs in the indoor DPs were as follows, 655.5 µg g-1 for Zn, 114.6 µg g-1 for Cu, 77.7 µg g-1 for Cr, 108.6 µg g-1 for Ni, 52 µg g-1 for Pb, 12 µg g-1 for Co, and 3.3 µg g-1 for Cd, while the average concentration of Zn, Cu, Cr, Ni, Pb, Co, Cd in the outdoor DPs were 293.7 µg g-1, 200.6 µg g-1, 100.7 µg g-1, 68.4 µg g-1, 44.7 µg g-1, 18.6 µg g-1, 0.25 µg g-1, respectively. A higher concentration of HMs, as well as cytotoxicity, were revealed in the indoor samples compared to outdoor ones. The degree of cytotoxicity of DPs collected from high-traffic areas was higher than that of low and medium-traffic ones. In addition, treatment of AGS and L929 cells with indoor dust samples induced the expression level of inflammatory agents such as TNFα, IL6, and, CYP1A1 genes more than in outdoor dust samples (P < 0.05). Briefly, a higher level of HMs concentration and cytotoxicity effect on the given cell lines was observed in the samples taken from indoor environments and high-traffic areas.

Spatial distribution, driving factors and health risks of fine particle-bound polycyclic aromatic hydrocarbons (PAHs) from indoors and outdoors in Hefei, China.

Atmospheric particulate matter, especially in urban and industrial environments, can act as a source of different organic pollutants that can pose significant health impacts to residents. However, the pollution status and transport mechanisms of fine particle-bound polycyclic aromatic hydrocarbons (PAHs) in indoor and outdoor environments are uncertain. This study aimed to determine the spatial distribution and morphological characteristics of fine particle-bound PAHs and analyze the factors (source contributions and backward trajectories) that influence their concentrations. The results showed that mean concentrations of 16 PAHs were higher in indoor dust as compared to outdoor dust. In addition, the lowest concentrations of the 16 PAHs were found on the 11-20th floor, with smoking households > nonsmoking households (except Nap, Acy, and Ace). The 2-3 ring PAHs were more prominent in households with cooking activities. The particle size distribution showed that most of the particles were <62 µm in diameter, indicating that the indoor particles were smaller in size. Furthermore, the range of δ13C values in the outdoor dust (-30.17 ~ -28.63 ‰) samples was significantly lower than in indoor dust (-28.29 ~ -22.53 ‰). The results based on diagnostic ratios, positive matrix factorization (PMF) analysis and backward trajectory model analysis suggested that the sources of PAHs in indoor and outdoor dust were mixed, originated both locally and from neighboring provinces transported over long distances, especially concentrated in the Yangtze River Delta area. Finally, carcinogenic risk values for indoor dust were greater than those for outdoor dust. Therefore, it is recommended that local governments and industries with high PAH emissions should implement proper protocols to monitor and minimize the pollution levels of PAHs in the urban industrial environment in order to mitigate their health risks.

Potential ecological and health risks of heavy metals for indoor and corresponding outdoor dust in Hefei, Central China.

The harm caused by indoor dust has received increasing attention in recent years. However, current studies have ignored comparisons with the corresponding outdoor dust. This study aimed to investigate the distribution of heavy metals in indoor and corresponding outdoor dust and the ecological and health risks they pose in Hefei, Central China. We analyzed O/I (outdoor/indoor concentration ratios) values, background comparison, and correlation analysis (heavy metal concentrations vs. particle size) and found that Cu, Zn, and Cd mainly existed in indoor sources, while V, Co, and As mainly existed in outdoor sources, and both family sizes and floor number influenced the variation of O/I. Through a new potential ecological risk assessment method, we determined that Cd risk levels in indoor and outdoor dust were extreme and high to extreme, respectively. Additionally, the carcinogenic risks of Ni, As, and Cr were not negligible. The risk of indoor dust was higher than that of outdoor dust for the heavy metals studied, implying a poor indoor environment. Notably, indoor dust from families with smaller sizes, lower floors, and smokers had higher ecological and carcinogenic risks.

Distribution, source apportionment and health risk assessment of phthalate esters in outdoor dust samples on Tibetan Plateau, China.

The urbanization of Tibetan Plateau (TP) probably results in a significant contamination of organic pollutants in the area, such as phthalate esters (PAEs). However, there is a lack of monitoring and evaluation of their occurrence and risks in the outdoor dust on TP. This study for the first time investigated the concentrations, distributions and health risk of PAEs in outdoor dust samples on TP, China. A total of 132 outdoor dust samples were collected from five different functional areas, and results showed the ubiquitous detection of all PAEs in the samples. The Σ6PAEs concentrations ranged from 0.08 to 31.49 µg·g-1 with a mean of 3.57 µg·g-1. High concentrations of Σ6PAEs in the outdoor dust were found in commercial districts, which were attributed to the heavy use of PAEs in the public commerce such as consumer products, commodities, and building materials. Di-n-butyl phthalate (DBP) and bis(2-ethylhexyl) phthalate (DEHP) were the dominant components accounting for 30.65% and 53.19% of the Σ6PAEs. Principal component analysis, positive matrix factorization, and correlation analysis were used to apportion the potential sources of PAEs in outdoor dust samples. The PAEs in the outdoor dust originated mainly from wide application of plasticizers as well as cosmetics and personal care products. The main pathways of human exposure to PAEs in the outdoor dust were ingestion and dermal absorption of dust particles. The total intakes of PAEs from outdoor dusts for children and adults were 1.50 × 10-5 and 2.47 × 10-6 mg·kg-1·d-1, respectively. Children were more susceptible to the PAEs intake than the adults. Although the estimated health risks of the six PAEs are currently acceptable, caution is needed given the likely future increase in use of these PAEs and the currently unknown contribution to human exposure by other medium.

Source identification of pollution and health risks to metals in household indoor and outdoor dust: A cross-sectional study in a typical mining town, China.

Dust is regarded as an important pathway of heavy metal(loid)s to the human body. Health risks posed by metal(loid)s from household dust are of particular concern. However, the contamination and sources of heavy metal(loid)s in household dust environments, as well as source identification of health risks related to heavy metal(loid)s from household dust for vulnerable populations such as children, have not been thoroughly studied in China, particularly for the areas involved with industrial activities such as ore mining. Thus, a cross-sectional study was conducted in a rural area famous for Pb/Zn ore mining, to assess the pollution sources and health risks of heavy metal(loid)s from household indoor and outdoor dust and to identify the contribution of household dust to the health risks for children. The results indicated that household environment was heavily contaminated by metal(loid)s, which were mainly attributed to mining activity. Meanwhile, the indoor/outdoor ratio and the redundancy analysis indicated that there were other pollution sources in indoor environments such as coal combustion, materials for interior building and decoration. Vapor inhalation was the main exposure pathway for Hg, while ingestion was the predominant pathway for other metal(loid)s. Although the cancer risks were relatively low, the HIt from household indoor and outdoor dust (2.19) was about twice the acceptable limit (1) and was primarily from Pb (64.52%) and As (23.42%). Outdoor dust was a larger contributor to the HI of Sb, As, Cr, Cd, Zn and Pb, which accounted for 51.37%, 58.63%, 52.14%, 59.66%, 52.87% and 64.47%, respectively, and the HIt was mainly from outdoor dust (60.76%). These results indicated that non-cancer health risks were largely from outdoor dust exposure, and strengthened the notion that concern should be given to the potential health risks from metal(loid)s in household dust both originating from mining activity and indoor environmental sources.

Occurrence, Distribution, and Human Exposure of Emerging Liquid Crystal Monomers (LCMs) in Indoor and Outdoor Dust: A Nationwide Study.

Liquid crystal monomers (LCMs) are a class of emerging, persistent, bioaccumulative, and toxic organic pollutants. They are detected in various environmental matrixes that are associated with electronic waste (e-waste) dismantling. However, their occurrence and distribution in indoor and outdoor dust on a national scale remain unknown. In this study, a dedicated target analysis quantified a broad range of 60 LCMs in dust samples collected across China. The LCMs were frequently detected in indoor (n = 48) and outdoor dust (n = 97; 37 sampled concomitantly with indoors dust) from dwellings, and indoor dust from cybercafés (n = 34) and phone repair stores (n = 22), with median concentrations of 41.6, 94.7, 106, and 171 ng/g, respectively. No significant spatial difference was observed for the concentrations of the total LCMs among distinct geographical regions (p > 0.05). The median daily intake values of the total LCMs via dust ingestion, dermal contact, and inhalation were estimated at 1.50 × 10-2, 2.90 × 10-2, and 8.57 × 10-6 ng/kg BW/day for adults and 1.47 × 10-1, 1.22 × 10-1, and 2.18 × 10-5 ng/kg BW/day for children, respectively. These estimates suggested higher exposure risks for children and indicated that dust ingestion and dermal contact significantly contribute to the human intake of LCMs. The microenvironmental pollution levels of LCMs together with the potential exposure risks associated with some of these chemicals are of concern for human health.

Pesticide screening and health risk assessment of residential dust in a rural region of the North China Plain.

Pesticides that have accumulated in arable soil could be easily transported by wind erosion, thereby potentially threating air quality and human health in surrounding areas. The risks this poses to farmers exposed to pesticide-associated dust is still unknown, especially in rural areas of China. In this study, we screened pesticide residues in dust (indoor and outdoor) collected from the homes and yards of pesticide sprayers (21 participants) and farm workers (14 participants) living in Quzhou County located in the North China Plain to assess health risks by exposed to pesticide-contaminated dust. The results showed that multiple pesticide residues were detected in the dust samples and more than 90% of the samples contained over 10 pesticide residues. The maximum detected number of residues was 23, out of the 25 pesticides currently used in the farming area. There was a wide range of pesticide concentrations with the geometric mean values measuring between 0.03 and 0.86 mg kg-1. More residues and higher concentrations of pesticides were detected in indoor dust compared to outdoor dust. Over the monitoring period, the pesticide application has not caused significant pesticide accumulation in dust. The measured concentrations of carbendazim, dimethomorph, dimethomorph and pendimethalin paired indoor-outdoor dust samples were significantly correlated (p < 0.05). The health risks were assessed using the hazard index (HI) and highest HI was found for children under indoor exposure (HI = 0.82). In addition, based on the survey and statistics, pesticide preparation in the home was significantly correlated with the pesticide indoor exposure level. Therefore, farmers should take measures, such as preparing pesticides outside of the house or in the open fields with protection, in order to avoid the exposure risk of pesticides associated with dust.

Occurrence, distribution and health risk assessment of organophosphate esters in outdoor dust in Nanjing, China: Urban vs. rural areas.

With increasing use of organophosphate esters (OPEs) largely due to the phasing out of various brominated flame retardants, much more attention has been paid to their occurrence, distribution and potential health risks. In this study, we investigated the occurrence and distribution characteristics associated to their potential health risks of selected 13 OPEs in outdoor dust with a comparison between urban and rural areas in Nanjing, China as well as seasonal variations. Ten out of 13 OPEs showed higher concentrations in urban dust than those in rural dust (p < 0.05). Six OPEs congeners exhibited significantly different concentrations with seasonal variations (p < 0.01) in rural dust. Halogenated OPEs were the dominant group in both urban (median: 56.8%) and rural (median: 45.9%) dust, and tris(2-chloroisopropyl) phosphate (TCPP) was found to be the most abundant OPE in both urban (median: 48.7%) and rural (median:26.4%) dust. Principal component analysis with multiple linear regression (PCA-MLR) and spearman correlations showed the different sources of OPEs in urban and rural dust. The non-carcinogenic (Hazard Index, HI < 1.62 × 10-5) and carcinogenic risks (CR < 2.28 × 10-9) of ΣOPEs were much lower than the theoretical threshold of risk, revealing a negligible risk to local residents from the exposure of OPEs in outdoor dust.

Perfluoroalkyl acids (PFAAs) in indoor and outdoor dusts around a mega fluorochemical industrial park in China: Implications for human exposure.

The manufacture of fluorochemicals can lead to high levels of perfluoroalkyl acids (PFAAs) contaminating the surrounding environment and consequently elevated exposure to the local residents. In this study, measurements of PFAAs associated with indoor and outdoor dusts around a mega fluorochemical industrial park (FIP) were made. Perfluorooctanoic acid (PFOA) and short-chain perfluoroalkyl carboxylic acids (C4-C7 PFCAs) were the predominant forms in all samples. The signature of the PFAAs in dusts in the local area matched that found within the FIP complex. The contamination plume in the local area could be linked to the prevailing wind direction starting from the FIP. The dust concentrations decreased exponentially with distance from the FIP (noticeably in the first 5km). PFAAs contamination could be detected at the furthest location, 20km away from the FIP. The concentrations of PFAAs were higher in indoor dust (73-13,500ng/g, median: 979ng/g) than those in outdoor dust (5-9495ng/g, median: 62ng/g) at every location. The highest estimated daily intake of PFOA via dust ingestion (26.0ng/kg·bw/day) was for toddlers (2-5years) living 2km away from the FIP, which is posing human health risk, though exposure remains within the provisional tolerable daily intake values.

Polybrominated diphenyl ethers (PBDEs) in soil and outdoor dust from a multi-functional area of Shanghai: levels, compositional profiles and interrelationships.

In this study, 14 polybrominated diphenyl ethers (PBDEs) congeners were investigated in soil and outdoor dust taken from Jiading District, Shanghai City. The concentrations of Σ13PBDEs (BDE-17, BDE-28, BDE-47, BDE-66, BDE-71, BDE-85, BDE-99, BDE-100, BDE-138, BDE-153, BDE-154, BDE-183 and BDE-190) and BDE-209 ranged from 0.37 to 32.9ngg(-1) and 4.31 to 141.8ngg(-1) dry weight (dw) in soil. Concentrations in outdoor dust ranged from 1.03 to 112.5ngg(-1) and 6.71 to 342.1ngg(-1) (dw) for Σ13PBDEs and BDE-209. BDE-209 was the predominant congener both in soil and outdoor dust, but the BDE-209 contribution was much lower in dust compared with that in soil. A significant correlation between PBDEs congeners and specific land use type was observed, and principal component analysis (PCA) revealed that the major source of PBDE in samples was associated with prevalent use of technical Deca-BDE, which also suggested the contributions from Penta-BDE and Octa-BDE mixtures. Canonical correlation analysis suggested the two sets of PBDEs data (soil and outdoor dust) were uncorrelated, and Spearman correlation coefficient matrix implied that the degradation pathways of PBDEs were different between soil and outdoor dust.

Occurrence and exposure evaluation of perchlorate in outdoor dust and soil in mainland China.

A total of 98 paired soil and outdoor dust samples were collected across mainland China for survey of perchlorate. Perchlorate was detected in all of the soil and outdoor dust samples. High levels of perchlorate were found in soil, ranging from 0.001 to 216 mg/kg in Northern China and from 0.001 to 25.8 mg/kg in Southern China. Even higher perchlorate concentrations were detected in dust samples, with concentrations ranging from 0.132 to 5,300 mg/kg in Northern China, and from 0.270 to 3,700 mg/kg in Southern China. This is the first known report of perchlorate in dust samples. The high perchlorate levels in soil and dust may raise concern on the potential risk for organisms and human. The daily perchlorate intakes were evaluated based on our measured perchlorate concentrations via inhalation, ingestion, and dermal contact of soil and dust for both children and adults, respectively. In general, the exposure from soil does not appear to lead to perchlorate intakes exceeding the US EPA reference for both children and adults. However, children can be at risk from exposure to perchlorate via dust, and it needs considerable concern for both children and adults at the sites with high dust perchlorate concentrations. After comparison with other possible exposure pathways, such as from drinking water, we suggested that dust may be an important potential source of perchlorate exposure in China, and further study is needed, especially for indoor dust.

Distribution of artificial sweeteners in dust and soil in China and their seasonal variations in the environment of Tianjin.

A nationwide investigation on the occurrence of artificial sweeteners (ASs) was conducted by collecting 98 paired outdoor dust and soil samples from mainland China. The ASs were widely detected in Chinese atmospheric dry deposition and soil samples, at concentrations up to 6450 and 1280 ng/g, respectively. To give a picture on AS distribution and source in the whole environment, the concentrations and seasonal variations of ASs in Tianjin were studied, including atmosphere, soil, and water samples. The AS levels were significantly higher in Haihe river at TJW (a sampling site in central city) in winter, while no obviously seasonal trends were obtained at BYL (close to a AS factory) and the site at a wastewater treatment plant. Saccharin, cyclamate, and acesulfame were the dominant ASs in both gas and particulate phase, with concentrations varying from 0.02 to 1940 pg/m(3). Generally, gas phase concentrations of the ASs were relatively higher in summer, while opposite results were acquired for particulate phase. Wet and dry deposition fluxes were calculated based on the measured AS levels. The results indicated that both wet and dry deposition could efficiently remove ASs in the atmosphere and act as important pollutant sources for the ASs in surface environment.