1.
Z Naturforsch C J Biosci
; 73(1-2): 59-66, 2018 Jan 26.
Artículo
en Inglés
| MEDLINE
| ID: mdl-29161234
RESUMEN
(9Z)-Methyl 4-dihydrotrisporate B and (9Z)-methyl trisporate B, pheromones of Zygomycetes fungi, have been synthesized using Stille cross-coupling from previously described cyclohexenone precursors. Conducting the coupling without protection groups allowed for a short and stereospecific synthesis route of the late trisporoids. Stability studies for both the compounds revealed (9Z)-methyl trisporate B to be very unstable against UV irradiation.