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Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions.
Pignataro, Luca; Lynikaite, Benita; Colombo, Raffaele; Carboni, Stefano; Krupicka, Martin; Piarulli, Umberto; Gennari, Cesare.
Affiliation
  • Pignataro L; Dipartimento di Chimica Organica e Industriale, Centro Interdipartimentale C.I.S.I., Università degli Studi di Milano, Via G. Venezian 21, 20133 Milano, Italy.
Chem Commun (Camb) ; (24): 3539-41, 2009 Jun 28.
Article in En | MEDLINE | ID: mdl-19521600
ABSTRACT
Heteroleptic complexes, formed selectively by using a 1 1 combination of a sigma-donor and a pi-acceptor ligand, are involved in Rh- and Pd-catalysed reactions.
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Full text: 1 Database: MEDLINE Language: En Year: 2009 Type: Article
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Full text: 1 Database: MEDLINE Language: En Year: 2009 Type: Article