Characterization of a rhodium-sparteine complex, [((-)-sparteine)Rh(eta4-COD)]+: crystal structure and DNMR/DFT studies on ligand-rotation dynamics.

De Crisci, Antonio G; Annibale, Vincent T; Hamer, Gordon K; Lough, Alan J; Fekl, Ulrich

De Crisci, Antonio G; Annibale, Vincent T; Hamer, Gordon K; Lough, Alan J; Fekl, Ulrich.

Affiliation

De Crisci AG; UTM, Department of Chemical and Physical Sciences, University of Toronto, 3359 Mississauga Road N, Mississauga, Ontario, Canada L5L 1C6.

Dalton Trans ; 39(11): 2888-902, 2010 Mar 21.

Article in En | MEDLINE | ID: mdl-20200717

Subject(s)

Coordination Complexes/chemistry; Ligands; Organometallic Compounds/chemistry; Rhodium/chemistry; Sparteine/chemistry; Coordination Complexes/chemical synthesis; Crystallography, X-Ray; Magnetic Resonance Spectroscopy; Molecular Conformation; Molecular Dynamics Simulation; Thermodynamics

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Full text: 1 Database: MEDLINE Main subject: Organometallic Compounds / Rhodium / Sparteine / Coordination Complexes / Ligands Language: En Year: 2010 Type: Article

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Full text: 1 Database: MEDLINE Main subject: Organometallic Compounds / Rhodium / Sparteine / Coordination Complexes / Ligands Language: En Year: 2010 Type: Article