Directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(II)-tris(bathophenanthroline-disulfonate).

Trammell, Scott A; Tsoi, Stanislav; Martin, Brett; Melde, Brian J; Moore, Martin M; Dressick, Walter J

Trammell, Scott A; Tsoi, Stanislav; Martin, Brett; Melde, Brian J; Moore, Martin M; Dressick, Walter J.

Affiliation

Trammell SA; Center for Bio/Molecular Science & Engineering, Naval Research Laboratory, Code 6900, Washington, DC, USA. scott.trammell@nrl.navy.mil

Chem Commun (Camb) ; 47(40): 11348-50, 2011 Oct 28.

Article in En | MEDLINE | ID: mdl-21927757

ABSTRACT

ABSTRACT

We have demonstrated directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(II)-tris(bathophenanthroline-disulfonate (RuBPS). The films were made by electrochemically-induced hydrolysis of a silane analogue of paraquat with ruthenium(II)-tris(bathophenanthroline-disulfonate as its ion pair.

Subject(s)

Organometallic Compounds/chemistry; Paraquat/chemistry; Photochemical Processes; Silicates/chemistry; Electrochemistry; Electron Transport

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Full text: 1 Database: MEDLINE Main subject: Organometallic Compounds / Paraquat / Silicates / Photochemical Processes Language: En Year: 2011 Type: Article

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Full text: 1 Database: MEDLINE Main subject: Organometallic Compounds / Paraquat / Silicates / Photochemical Processes Language: En Year: 2011 Type: Article