Stereocontrolled Total Syntheses of (-)-Rotenone and (-)-Dalpanol by 1,2-Rearrangement and S<sub>N</sub> Ar Oxycyclizations.

Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke

Stereocontrolled Total Syntheses of (-)-Rotenone and (-)-Dalpanol by 1,2-Rearrangement and S_N Ar Oxycyclizations.

Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke.

Affiliation

Nakamura K; Department of Chemistry, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo, 152-8551, Japan.
Ohmori K; Department of Chemistry, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo, 152-8551, Japan.
Suzuki K; Department of Chemistry, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo, 152-8551, Japan.

Angew Chem Int Ed Engl ; 56(1): 182-187, 2017 01 02.

Article in En | MEDLINE | ID: mdl-27910179

Subject(s)

Biological Products/chemical synthesis; Heterocyclic Compounds, 4 or More Rings/chemical synthesis; Rotenone/chemical synthesis; Biological Products/chemistry; Chemistry Techniques, Synthetic/methods; Cyclization; Derris/chemistry; Heterocyclic Compounds, 4 or More Rings/chemistry; Rotenone/analysis; Stereoisomerism

Key words

cyclizations; heterocycles; natural products; rearrangements; total synthesis

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Full text: 1 Database: MEDLINE Main subject: Rotenone / Biological Products / Heterocyclic Compounds, 4 or More Rings Language: En Year: 2017 Type: Article

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Full text: 1 Database: MEDLINE Main subject: Rotenone / Biological Products / Heterocyclic Compounds, 4 or More Rings Language: En Year: 2017 Type: Article