Synthesis of Phenylpropanoids via Matsuda-Heck Coupling of Arene Diazonium Salts.
J Org Chem
; 82(8): 4386-4395, 2017 04 21.
Article
in En
| MEDLINE
| ID: mdl-28394127
ABSTRACT
The Pd-catalyzed Heck-type coupling (Matsuda-Heck reaction) of electron rich arene diazonium salts with electron deficient olefins has been exploited for the synthesis of phenylpropanoid natural products. Examples described herein are the naturally occurring benzofurans methyl wutaifuranate, wutaifuranol, wutaifuranal, their 7-methoxy derivatives, and the O-prenylated natural products boropinols A and C.
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MEDLINE
Language:
En
Year:
2017
Type:
Article