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Synthesis of fluoroalkylated alkynes via visible-light photocatalysis.
Iqbal, Naila; Iqbal, Naeem; Han, Sung Su; Cho, Eun Jin.
Affiliation
  • Iqbal N; Department of Chemistry, Chung-Ang University, 84 Heukseok-ro, Dongjak-gu, Seoul 06974, Republic of Korea. ejcho@cau.ac.kr.
Org Biomol Chem ; 17(7): 1758-1762, 2019 02 13.
Article in En | MEDLINE | ID: mdl-30427049
ABSTRACT
Fluoroalkylated alkynes, which are versatile building blocks for the synthesis of various biologically active organofluorine compounds, were synthesized from easily available alkynyl halides and fluoroalkyl halides by visible-light photocatalysis. Addition of fluoroalkyl radicals to alkynes and subsequent dehalogenation selectively yielded fluoroalkylated alkynes.
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Full text: 1 Database: MEDLINE Language: En Year: 2019 Type: Article
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Full text: 1 Database: MEDLINE Language: En Year: 2019 Type: Article