Probing the gas-phase structure of charge-tagged intermediates of a proline catalyzed aldol reaction - vibrational spectroscopy distinguishes oxazolidinone from enamine species.

Willms, J Alexander; Vidic, Jandro; Barthelmes, Janosch; Steinmetz, Vincent; Bredow, Thomas; Maître, Philippe; Engeser, Marianne

Willms, J Alexander; Vidic, Jandro; Barthelmes, Janosch; Steinmetz, Vincent; Bredow, Thomas; Maître, Philippe; Engeser, Marianne.

Affiliation

Willms JA; Kekulé-Institute of Organic Chemistry and Biochemistry, University of Bonn, Gerhard-Domagk-Straße 1, D-53121 Bonn, Germany. marianne.engeser@uni-bonn.de.

Phys Chem Chem Phys ; 21(5): 2578-2586, 2019 Jan 30.

Article in En | MEDLINE | ID: mdl-30657479

Subject(s)

Gases/chemistry; Oxazolidinones/chemistry; Proline/chemistry; Aldehydes/chemistry; Catalysis; Chemistry Techniques, Synthetic/methods; Density Functional Theory; Malonates/chemistry; Mass Spectrometry/methods; Models, Chemical; Vibration

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