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From Planar Macrocycle to Cylindrical Molecule: Synthesis and Properties of a Phenanthrene-Based Coronal Nanohoop as a Segment of [6,6]Carbon Nanotube.
Cui, Shengsheng; Huang, Qiang; Wang, Jinyi; Jia, Hongxing; Huang, Pingsen; Wang, Shengda; Du, Pingwu.
Affiliation
  • Cui S; Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, iChEM, Department of Materials Science and Engineering , University of Science and Technology of China (USTC) , 96 Jinzhai Road , Hefei , Anhui Province 230026 , China.
  • Huang Q; Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, iChEM, Department of Materials Science and Engineering , University of Science and Technology of China (USTC) , 96 Jinzhai Road , Hefei , Anhui Province 230026 , China.
  • Wang J; Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, iChEM, Department of Materials Science and Engineering , University of Science and Technology of China (USTC) , 96 Jinzhai Road , Hefei , Anhui Province 230026 , China.
  • Jia H; Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, iChEM, Department of Materials Science and Engineering , University of Science and Technology of China (USTC) , 96 Jinzhai Road , Hefei , Anhui Province 230026 , China.
  • Huang P; Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, iChEM, Department of Materials Science and Engineering , University of Science and Technology of China (USTC) , 96 Jinzhai Road , Hefei , Anhui Province 230026 , China.
  • Wang S; Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, iChEM, Department of Materials Science and Engineering , University of Science and Technology of China (USTC) , 96 Jinzhai Road , Hefei , Anhui Province 230026 , China.
  • Du P; Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, iChEM, Department of Materials Science and Engineering , University of Science and Technology of China (USTC) , 96 Jinzhai Road , Hefei , Anhui Province 230026 , China.
Org Lett ; 21(15): 5917-5921, 2019 Aug 02.
Article in En | MEDLINE | ID: mdl-31329458
ABSTRACT
Herein, we explore phenanthrene as the building block to synthesize a hoop-shaped [6,6]carbon nanotube segment from a planar macocycle via a Diels-Alder reaction. The phenanthrene-based coronal nanohoop 7 was fully characterized by HR-MS, NMR, and other spectroscopies. In addition, its photophysical properties and the supramolecular interactions between 7 and fullerene C60 were investigated. This present work suggests an easily accessible Diels-Alder reaction strategy to synthesize cylindrical nanohoops.
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Full text: 1 Database: MEDLINE Language: En Year: 2019 Type: Article
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Full text: 1 Database: MEDLINE Language: En Year: 2019 Type: Article