Glycosyl selenoacetates: versatile building blocks for the preparation of stereoselective selenoglycosides and selenium linked disaccharides.
Org Biomol Chem
; 17(39): 8902-8912, 2019 10 21.
Article
in En
| MEDLINE
| ID: mdl-31553009
ABSTRACT
Glycosyl selenoacetate derivatives were prepared by the treatment of glycosyl halide with potassium selenocyanate followed by acetylation of in situ generated glycosyl selenols in one pot. A variety of selenoglycosides and selenium linked disaccharide derivatives were prepared in very good to excellent yields using glycosyl selenoacetates as stable building blocks under mild reaction conditions.
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Database:
MEDLINE
Language:
En
Year:
2019
Type:
Article