Differential Adsorption of l- and d-Lysine on Achiral MFI Zeolites as Determined by Synchrotron X-Ray Powder Diffraction and Thermogravimetric Analysis.
Angew Chem Int Ed Engl
; 59(3): 1093-1097, 2020 01 13.
Article
in En
| MEDLINE
| ID: mdl-31701612
ABSTRACT
Reported here is the first crystallographic observation of stereospecific bindings of l- and d-lysine (Lys) in achiral MFI zeolites. The MFI structure offers inherent geometric and internal confinement effects for the enantiomeric difference in l- and d-Lys adsorption. Notable differences have been observed by circular dichroism (CD) spectroscopy and thermogravimetric analysis (TGA). Distinct l- and d-Lys adsorption behaviours on the H-ZSM-5 framework have been revealed by the Rietveld refinement of high-resolution synchrotron X-ray powder diffraction (SXRD) data and the density-functional theory (DFT) calculations. Despite demonstrating the approach for l- and d-Lys over MFI zeolites at an atomistic resolution, the differential adsorption study sheds light on the rational engineering of molecular interaction(s) with achiral microporous materials for chiral separation purposes.
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Database:
MEDLINE
Language:
En
Year:
2020
Type:
Article