Simultaneous determination of nitrophenol isomers based on reduced graphene oxide modified with sulfobutylether-ß-cyclodextrin.

ABSTRACT

The present study reports the development of an electrochemical sensor based on sulfobutylether-ß-cyclodextrin modified reduced graphene oxide hybrid (SBCD-rGO) for simultaneous detection of nitrophenol isomers. First, SBCD-rGO hybrid was synthesized and detailed characterized. Afterwards, a sensor was fabricated via the modification of glassy carbon electrode (GCE) with SBCD-rGO, and its electrochemical detection performances were also investigated. Then, the constructed electrochemical sensor was applied to detect nitrophenol isomers by voltammetry analysis. The results suggested that the sensitivities were 389.26, 280.88 and 217.19 µA/mM for p-nitrophenol (p-NP), m-nitrophenol (m-NP), and o-nitrophenol (o-NP), respectively, and their corresponding detection limits were all about 0.05 µM. Significantly, the combination of voltammetry analysis with the constructed sensor and data analysis by multiple linear regression realized the simultaneous detection of nitrophenol isomers.