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Supramolecular Modifying Nafion with Fluoroalkyl­Functionalized Polyoxometalate Nanoclusters for High­Selective Proton Conduction.
He, Haibo; Song, Shihao; Zhai, Liang; Li, Zexu; Wang, Sihan; Zuo, Peng; Zhu, Youliang; Li, Haolong.
Affiliation
  • He H; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
  • Song S; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
  • Zhai L; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
  • Li Z; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
  • Wang S; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
  • Zuo P; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
  • Zhu Y; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
  • Li H; State Key Laboratory of Supramolecular Structure and Materials College of Chemistry, Jilin University, Qianjin Avenue 2699, Changchun, 130012, China.
Angew Chem Int Ed Engl ; : e202409006, 2024 Jun 19.
Article in De | MEDLINE | ID: mdl-38896505
ABSTRACT
Fluoroalkyl-grafted polyoxometalate nanoclusters are used as supramolecular additives to precisely modify the ionic domains of Nafion, which can increase the proton conductivity and selectivity simultaneously. The resulting hybrid membranes show significantly enhanced power density in fuel cells and improved energy efficiency in vanadium flow batteries.
Key words

Full text: 1 Database: MEDLINE Language: De Year: 2024 Type: Article

Full text: 1 Database: MEDLINE Language: De Year: 2024 Type: Article