A new supported reagent for the photochemical generation of radicals in solution.
Org Lett
; 3(6): 855-7, 2001 Mar 22.
Article
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| MEDLINE
| ID: mdl-11263899
ABSTRACT
A new polymer-supported radical source was developed by loading an N-hydroxy thiazole 2(3)-thione on a Wang resin. This new supported reagent can be employed for a solid-phase version of the Hunsdiecker reaction or to liberate free alkoxy radicals, in a variant of the "catch and release" technique, under very mild conditions (irradiation with a discharge lamp) and simplifying the purification procedure.