Fine structural photoluminescence spectra of silica-supported zirconium oxide and its photoactivity in direct methane conversion.

Yoshida, Hisao; Chaskar, Manohar G; Kato, Yuko; Hattori, Tadashi

Yoshida, Hisao; Chaskar, Manohar G; Kato, Yuko; Hattori, Tadashi.

Afiliación

Yoshida H; Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan. yoshidah@apchem.nagoya-u.ac.jp

Chem Commun (Camb) ; (18): 2014-5, 2002 Sep 21.

Article en En | MEDLINE | ID: mdl-12357756

ABSTRACT

ABSTRACT

Highly dispersed zirconium oxide species on silica exhibit fine structure in phosphorescence emission spectra showing the vibration energy of the photoactive Zr-O-Si linkage to be 955 cm-1, and the species promotes the photoinduced non-oxidative methane coupling at room temperature.

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Banco de datos: MEDLINE Idioma: En Año: 2002 Tipo del documento: Article

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Banco de datos: MEDLINE Idioma: En Año: 2002 Tipo del documento: Article