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Bis{N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline-κP,P'}copper(I) tetra-fluoridoborate.
Acta Crystallogr Sect E Struct Rep Online ; 67(Pt 1): m96, 2010 Dec 18.
Article en En | MEDLINE | ID: mdl-21522609
ABSTRACT
In the cation of the title compound, [Cu(C(32)H(29)NP(2))(2)]BF(4), the Cu(I) atom is four-coordinated in a distorted tetra-hedral geometry by four P atoms from two N,N-bis-[(diphenyl-phosphan-yl)meth-yl]aniline ligands. In the crystal, the cations are linked by C-H⋯π inter-actions, forming chains along the a axis. Intra-molecular C-H⋯N and inter-molecular C-H⋯F hydrogen bonds are also observed.