X-ray transient absorption and picosecond IR spectroscopy of fulvalene(tetracarbonyl)diruthenium on photoexcitation.
Angew Chem Int Ed Engl
; 51(31): 7692-6, 2012 Jul 27.
Article
en En
| MEDLINE
| ID: mdl-22740313
ABSTRACT
Caught in the light The fulvalene diruthenium complex shown on the left side of the picture captures sun light, causing initial Ru-Ru bond rupture to furnish a long-lived triplet biradical of synâ
configuration. This species requires thermal activation to reach a crossing point (middle) into the singlet manifold on route to its thermal storage isomer on the right through the antiâ
biradical.
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Banco de datos:
MEDLINE
Asunto principal:
Fármacos Fotosensibilizantes
/
Complejos de Coordinación
Tipo de estudio:
Prognostic_studies
Idioma:
En
Año:
2012
Tipo del documento:
Article