Unprecedented gallium-nitrogen anions: synthesis and characterization of [(Cl3Ga)3N]3- and [(Cl3Ga)2NSnMe3]2-.
Chem Commun (Camb)
; 49(44): 5049-51, 2013 Jun 04.
Article
en En
| MEDLINE
| ID: mdl-23625074
ABSTRACT
The [(Cl3Ga)3N](3-) (1) anion, which is the sole example of a discrete chemical species containing a µ3-N atom bound only to gallium, was isolated from the reaction of Cl3Ga·N(SnMe3)3 with [GaCl4](1-). The analogous reaction of [GaCl4](1-) with (Me3Sn)3N afforded [(Cl3Ga)2NSnMe3](2-) (2), which is also an unprecedented anion containing a single µ3-N atom bound to only gallium and tin.
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