Bias-dependent molecular-level structure of electrical double layer in ionic liquid on graphite.
Nano Lett
; 13(12): 5954-60, 2013.
Article
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| MEDLINE
| ID: mdl-24215396
ABSTRACT
Here we report the bias-evolution of the electrical double layer structure of an ionic liquid on highly ordered pyrolytic graphite measured by atomic force microscopy. We observe reconfiguration under applied bias and the orientational transitions in the Stern layer. The synergy between molecular dynamics simulation and experiment provides a comprehensive picture of structural phenomena and long and short-range interactions, which improves our understanding of the mechanism of charge storage on a molecular level.
Texto completo:
1
Banco de datos:
MEDLINE
Asunto principal:
Microscopía de Fuerza Atómica
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Líquidos Iónicos
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Grafito
Idioma:
En
Año:
2013
Tipo del documento:
Article