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Triple-Stranded Cluster Helicates for the Selective Catalytic Oxidation of C-H Bonds.
Fang, Yu; Gong, Wei; Liu, Lujia; Liu, Yan; Cui, Yong.
Afiliación
  • Fang Y; School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, China.
  • Gong W; School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, China.
  • Liu L; School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, China.
  • Liu Y; School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, China.
  • Cui Y; School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University , Shanghai 200240, China.
Inorg Chem ; 55(20): 10102-10105, 2016 Oct 17.
Article en En | MEDLINE | ID: mdl-27673441
ABSTRACT
Triple-stranded cluster helicates with heptametallic dicubane cores are synthesized by entrapping metals in the cavities of linear triple helicates based on a C2-symmetrical hexadentate Schiff-base ligand of ortho-substitued biphenol. The helicates are stable in both the solution and solid states, and the copper species could selectively catalyze the oxidation of C-H bonds of alkanes to ketones.
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Banco de datos: MEDLINE Idioma: En Año: 2016 Tipo del documento: Article
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Banco de datos: MEDLINE Idioma: En Año: 2016 Tipo del documento: Article