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Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity.
Bilyachenko, Alexey N; Levitsky, Mikhail M; Yalymov, Alexey I; Korlyukov, Alexander A; Khrustalev, Viktor N; Vologzhanina, Anna V; Shul'pina, Lidia S; Ikonnikov, Nikolay S; Trigub, Alexander E; Dorovatovskii, Pavel V; Bantreil, Xavier; Lamaty, Frédéric; Long, Jérôme; Larionova, Joulia; Golub, Igor E; Shubina, Elena S; Shul'pin, Georgiy B.
Afiliación
  • Bilyachenko AN; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Levitsky MM; People's Friendship University of Russia, Miklukho-Maklay Str., 6, 117198, Moscow, Russia.
  • Yalymov AI; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Korlyukov AA; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Khrustalev VN; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Vologzhanina AV; Pirogov Russian National Research Medical University, Ostrovitianov str., 1, Moscow, Russia.
  • Shul'pina LS; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Ikonnikov NS; People's Friendship University of Russia, Miklukho-Maklay Str., 6, 117198, Moscow, Russia.
  • Trigub AE; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Dorovatovskii PV; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Bantreil X; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, Moscow, Russia.
  • Lamaty F; National Research Center "Kurchatov Institute", Akademika Kurchatova pl., 1, Moscow, Russia.
  • Long J; National Research Center "Kurchatov Institute", Akademika Kurchatova pl., 1, Moscow, Russia.
  • Larionova J; Institut des Biomolécules Max Mousseron (IBMM), UMR 5247 CNRS, Université Montpellier, ENSCM CNRS, Université de Montpellier, ENSCM should be on the same line, Université de Montpellier Campus Triolet, Place Eugène Bataillon, 34095, Montpellier cedex 5, France.
  • Golub IE; Institut des Biomolécules Max Mousseron (IBMM), UMR 5247 CNRS, Université Montpellier, ENSCM CNRS, Université de Montpellier, ENSCM should be on the same line, Université de Montpellier Campus Triolet, Place Eugène Bataillon, 34095, Montpellier cedex 5, France.
  • Shubina ES; Institut Charles Gerhardt de Montpellier (ICGM), UMR5253, Equipe IMNO, Université de Montpellier, Site Triolet, Place Eugène Bataillon, 34095, Montpellier cedex 5, France.
  • Shul'pin GB; Institut Charles Gerhardt de Montpellier (ICGM), UMR5253, Equipe IMNO, Université de Montpellier, Site Triolet, Place Eugène Bataillon, 34095, Montpellier cedex 5, France.
Angew Chem Int Ed Engl ; 55(49): 15360-15363, 2016 12 05.
Article en En | MEDLINE | ID: mdl-27897426
ABSTRACT
A series of four unprecedented heterometallic metallagermsesquioxanes were synthesized. Their cage-like architectures have a unique type of molecular topology consisting of the hexairon oxo {Fe6 O19 } core surrounded in a triangular manner by three cyclic germoxanolates [PhGe(O)O]5 . This structural organization induces antiferromagnetic interactions between the FeIII ions through the oxygen atoms. Evaluated for this first time in catalysis, these compounds showed a high catalytic activity in the oxidation of alkanes and the oxidative formation of benzamides from alcohols.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2016 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2016 Tipo del documento: Article