Observation of current rectification by a new asymmetric iron(iii) surfactant in a eutectic GaIn|LB monolayer|Au sandwich.
Dalton Trans
; 47(18): 6344-6350, 2018 May 08.
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| ID: mdl-29633775
ABSTRACT
In this paper we expand on the search for molecular rectifiers of electrical current and report on a hexacoordinate metallosurfactant [FeIII(LN3O)(OMe)2], where (LN3O)- is the deprotonated form of the new asymmetric ligand 2-((E)-((4,5-bis(2-methoxyethoxy)-2-(((E)-pyridin-2-ylmethylene)amino)phenyl)imino)methyl)-4,6-di-tert-butyl-phenol. This species rectifies current when deposited as a Langmuir-Blodget film in a "EGaIn/Ga2O3|LB|Au" sandwich with rectification ratios ranging from 25 to 300 at 1 Volt.
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