Two-Step Azidoalkenylation of Terminal Alkenes Using Iodomethyl Sulfones.
Molecules
; 24(22)2019 Nov 18.
Article
en En
| MEDLINE
| ID: mdl-31752245
ABSTRACT
The radical azidoalkylation of alkenes that was initially developed with α-iodoesters and α-iodoketones was extended to other activated iodomethyl derivatives. By using iodomethyl aryl sulfones, the preparation of γ-azidosulfones was easily achieved. Facile conversion of these azidosulfones to homoallylic azides using a Julia-Kocienski olefination reaction is reported, making the whole process equivalent to the azidoalkenylation of terminal alkenes.
Palabras clave
Texto completo:
1
Banco de datos:
MEDLINE
Asunto principal:
Sulfonas
/
Azidas
/
Alquenos
Idioma:
En
Año:
2019
Tipo del documento:
Article