Solvent vapor-induced polarity and ferroelectricity switching.

Kobayashi, Fumiya; Akiyoshi, Ryohei; Kosumi, Daisuke; Nakamura, Masaaki; Lindoy, Leonard F; Hayami, Shinya

Kobayashi, Fumiya; Akiyoshi, Ryohei; Kosumi, Daisuke; Nakamura, Masaaki; Lindoy, Leonard F; Hayami, Shinya.

Afiliación

Kobayashi F; Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.

Chem Commun (Camb) ; 56(72): 10509-10512, 2020 Sep 16.

Article en En | MEDLINE | ID: mdl-32776059

ABSTRACT

ABSTRACT

Vapor-induced crystal to crystal transformation between non-polar [Fe(sap)(acac)(sol)] (H2sap = 2-salicylideneaminophenol, acac = acethylacetate, sol = MeOH, pyridine) and polar [Fe(sap)(acac)(DMSO)] was demonstrated. It provides an example of switchable ferroelectric behaviour attributted to the structural phase transition triggered by solvent vapour.

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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2020 Tipo del documento: Article

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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2020 Tipo del documento: Article