Effect of nano-metal doped calcium peroxide on biomass pretreatment and green hydrogen production from rice straw.
Bioresour Technol
; 386: 129489, 2023 Oct.
Article
en En
| MEDLINE
| ID: mdl-37460017
ABSTRACT
In this study, calcium peroxide was modified and doped with metal-based nanoparticles (NP) to enhance the efficiency of pretreatment and biohydrogen generation from RS. The findings revealed that the addition of MnO2-CaO2 NPs (at a dosage of 0.02 g/g TS of RS) had a synergistic effect on the breakdown of biomass and the production of biohydrogen. This enhancement resulted in a maximum hydrogen yield (HY) of 58 mL/g TS, accompanied by increased concentrations of acetic acid (2117 mg/L) and butyric acid (1325 mg/L). In contrast, RS that underwent pretreatment without the use of chemicals or NP exhibited a lower HY of 28 mL/g TS, along with the lowest concentrations of acetic acid (1062 mg/L) and butyric acid (697 mg/L). The outcome showed that supplementation of NP stimulated the pretreatment of RS and improved the formation of acetic and butyric acid through the regulation of metabolic pathways during acidogenic fermentation.
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MEDLINE
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Oryza
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En
Año:
2023
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Article