Unlocking single molecule magnetism: a supramolecular strategy for isolating neutral MnIII salen-type dimer in crystalline environments.
Dalton Trans
; 53(17): 7517-7521, 2024 Apr 30.
Article
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| MEDLINE
| ID: mdl-38597208
ABSTRACT
In [Mn(5-MeOsalen)(Cl)]2(dibenzo[24]crown-8), dibenzo[24]crown-8 formed a supramolecule via multi-point interactions with the [Mn(5-MeOsalen)(Cl)] dimer. The dimer was magnetically isolated with ST = 4 and weak interdimer magnetic interactions. The crystal exhibited single-molecule magnet behaviour with an anisotropic barrier of 26(1) K, which is the highest among the Mn-salen series reported to date.
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2024
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