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Chem Commun (Camb)
; 49(39): 4358-60, 2013 May 14.
Article
in English
| MEDLINE
| ID: mdl-23091820
ABSTRACT
Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes with an ene-1,2-dithiolate ligand are generated as models of the active sites of molybdenum hydroxylases. The sulfide and selenide groups are highly reactive toward triphenylphosphine in the order of Se > S.