Antioxidant and ammonia-sensitive films based on starch, κ-carrageenan and Oxalis triangularis extract as visual indicator of beef meat spoilage.

In this study, we first investigated the rheological property of sweet potato starch (SPS), κ-carrageenan (KC) and Oxalis triangularis extract (OTE) blends and found that the blends exhibited high apparent viscosity with an apparent shear thinning behavior. And then films based on SPS, KC and OTE were developed and their structural and functional properties were studied. The physico-chemical test results showed that OTE exhibited different colors in solutions with different pH values and the incorporation with OTE and KC could significantly increase the thickness, water vapor permeability, light barrier ability, tensile strength and elongation at break as well as the pH- and ammonia-sensitive properties of the SPS film. The structural property test results showed that some intermolecular interactions between OTE and SPS/KC occurred in SPS-KC-OTE films. Finally, the functional properties of SPS-KC-OTE films were examined and SPS-KC-OTE films showed significant DPPH radical scavenging activity as well as a visible color change in response to changes in beef meat freshness. Our results suggested that the SPS-KC-OTE films could be used as an active and intelligent food packaging material in food industry.

Preparation and characterization of antioxidant and pH-sensitive films based on arrowhead (Sagittaria sagittifolia) starch, κ-carrageenan and black chokeberry (Aronia melanocarpa) extract for monitoring spoilage of chicken wings.

In this study, we firstly developed an antioxidant and pH-sensitive film based on arrowhead starch (AS), κ-carrageenan (KC) and black chokeberry extract (BCE) and its physical and structural properties were investigated. We found BCE showed different colors in different pH solutions and incorporation with KC and BCE could significantly decrease light transmittance, increase thickness, elongation at break and pH-sensitive property of AS film. The results of structural property assay indicated that there were some intermolecular interactions between BCE and AS/KC in AS-KC-BCE films. Secondly, we investigated the rheological property of AS, AS-KC and AS-KC-BCE suspensions and found the suspensions showed an obvious shear-thinning behavior with high apparent viscosity. Finally, the functional properties of AS-KC-BCE films were investigated and AS-KC-BCE films showed strong scavenging activity on DPPH free radical and presented visible colour changes in response to the changes of the chicken wing qualities. The results suggest that AS-KC-BCE films can be used in active and intelligent packaging of food industry.

Guar gum/carboxymethyl cellulose based antioxidant film incorporated with halloysite nanotubes and litchi shell waste extract for active packaging.

The incorporation of bioactive extract from the food waste into biopolymers is a promising green approach to fabricate active films with antioxidant activity for food packaging. The present study developed bioactive antioxidant films based on guar gum/carboxymethyl cellulose incorporated with halloysite-nanotubes (HNT) and litchi shell extract (LSE). The effects of combining HNT and LSE on the physical, mechanical, and antioxidant properties of the films were analyzed. The results showed LSE caused a reduction in tensile strength; however, the elongation at break substantially improved from 29.93 to 62.12%. FTIR revealed covalent interaction and hydrogen bonding between guar gum/carboxymethyl cellulose and LSE. The XRD and SEM study confirmed interactions among the polymer matrix and LSE compounds. The addition of LSE to guar gum/carboxymethyl cellulose films notably increased the UV-light barrier properties. Moreover, the antioxidant activity of all GCH/LSE substantially improved from 9.46 to 91.52%, more than a ten-fold increase compared to composite neat GCH film. Finally, the oxidative stability of roasted peanuts packed in fabricated GCH/LSE sachets improved after 8 days. Guar gum/carboxymethyl cellulose containing LSE as an antioxidant agent could be applied as food packaging for low water activity oxygen-sensitive food.

Pineapple peel extract incorporated poly(vinyl alcohol)-corn starch film for active food packaging: Preparation, characterization and antioxidant activity.

This research study explores the fabrication of polyvinyl alcohol (PVOH) and corn starch (ST) with pineapple peel extract (PPE) as a natural antioxidant agent, which is an abundant by-product from the food processing industry via casting method. The effects of PPEs concentration (5%, 10%, 15%, and 20%) on the antioxidant capacity, optical, thermal, mechanical, barrier properties, and changes in PVOH-starch molecular structure of PVOH/ST films were investigated. The results revealed that with the increasing concertation of PPEs, prepared films' thickness and water vapor permeability slightly increased. Elongation at break of PVOH/ST films was also enhanced with PPEs concentration. All PPEs incorporated films exhibited enhanced thermal stability as the degradation occurred above 300 °C. The addition of PPE to PVOH/ST films remarkably increased the antioxidant properties. Finally, prepared PVOH/ST/PPE films demonstrated to be a capable material for developing active biodegradable packaging material due to its proven antioxidant activity and mechanical property, which can be helpful in the packaging of food products that gets spoiled due to oxidation reactions.

Development and characterization of PVA-starch incorporated with coconut shell extract and sepiolite clay as an antioxidant film for active food packaging applications.

An active antioxidant film was fabricated by using polyvinyl alcohol (PVA) and corn starch (ST) and incorporated with and 3, 5, 10, and 20% (v/v) coconut shell extract (CSE) and sepiolite clay (SP) for the first time. The microstructure and physical properties of prepared films were characterized and examined. The addition of sepiolite clay to PVA improved the elongation break 15.57 to 69.24%, and water vapor permeability increased with the addition of CSE. In addition to CSE to films, the antioxidant activity properties of the films were enhanced up to 80%. Further, increasing the amount of CSE slightly affected the color of the active films. The thermal properties of films were enhanced with the addition of CSE and SP. The dispersion of SP in the PVA matrix was affected by an increase in CSE concentration in the PVA matrix. Remarkably, PVA-ST film-based sachets successfully improved the oxidative stability of packaged soybean oil. Our results suggest PVA-ST film containing CSE and sepiolite clay can be utilized as a novel antioxidant packaging material in the food processing industry.

Development of antioxidant chitosan film with banana peels extract and its application as coating in maintaining the storage quality of apple.

In the present study, the antioxidant chitosan (CS)-banana peels extract (BPE) composite film was developed. The different content of BPE (4%, 8% and 12%) was added to the CS film not only as the antioxidant but also as the cross-linking. The CS, CS-4% BPE, CS-8% BPE and CS-12% BPE films were characterized by scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD) and thermogravimetric analysis (TGA). The physical and mechanical properties possessed by the CS and CS-BPE films were compared as well, and the CS-4 %BPE composite film exhibited the most excellent properties. The decline in moisture contents, water solubility and water vapor permeability of CS-BPE composite film indicated the reduced hydrophilicity. Moreover, the CS-BPE composite film exhibited excellent antioxidant activity in different food simulants. Finally, the optimal concentration of CS-BPE coating treatment was identified and applied to apple fruit, and the results showed that CS-BPE coating was more capable of improving the postharvest quality of apple fruit than CS coating. This study evidences the promising nature of CS-BPE composite film and coating as a desirable alternative for active packaging and it is believed as conducive to valorization of banana peel by-products for allied applications.