ABSTRACT
Advances in the development of gamma-ray spectrometers have resulted in devices that are ideal for use in conjunction with the increasingly reliable systems of autonomously flying uncrewed aerial vehicles (UAVs) that have recently become available on the market. Airborne gamma-ray spectrometry (GRS) measurements have many different applications. Here, the technique is applied to a former uranium mining and processing site, which is characterized by relatively low specific activities and, hence, low count rates, requiring relatively large detectors and correspondingly big size UAVs. The future acceptance of the use of such UAV-based GRS systems for radionuclide mapping depends on their ability to measure absolute specific activities of natural radionuclides such as U-238 in near-surface soil that are consistent with the results of established and proven ground-based systems. To determine absolute specific activities on the ground, the gamma radiation data from airborne detectors must be corrected for attenuation caused by the flight altitude above ground. In recent years, mathematical procedures for altitude correction have been developed, that are specifically tailored to the working range of several tens of meters typical for UAVs. However, very limited experimental validation of these theoretical approaches is available. A very large dataset consisting of about 3000 UAV-based and 19,000 backpack-based measurements was collected at a low-grade uranium ore dump in Yangiabad, Uzbekistan. We applied different geostatistical interpolation methods to compare the data from both survey techniques by upscaling backpack data to airborne data. Compared to backpack systems, UAV-based systems have lower spatial resolution, so measurements average over larger areal units (or in geostatistical terminology: "spatial support"). Taking into account the change in spatial support, we illustrate that (1) the UAV-based measurements show good agreement with the upscaled backpack measurements and that (2) UAV surveys provide good delineation of contrasts of the relatively smooth U-238 specific activity distribution typical for former uranium mining and processing sites. We are able to show that the resolution of UAV-based systems is sufficient to map extended uranium waste facilities.
Subject(s)
Radiation Monitoring , Soil Pollutants, Radioactive , Uranium , Uranium/analysis , Radiation Monitoring/methods , Soil Pollutants, Radioactive/analysis , Spectrometry, GammaABSTRACT
The acidification of agricultural soil in the southern part of the North China Plain has become more obvious, which is particularly true for the heavy clay soil types, such as yellow-cinnamon and lime concretion black soils. To understand the spatial variability of the pH value and nutrients on the vertical agricultural soil profile of heavy clay soils in this area, we measured pH values and available phosphorus (AP) in 63 farmland sample points from Xiping County in the southern Henan Province. Geostatistical methods and ArcGIS technology were used to map soil pH values along three soil depths (0-10, 10-20, and 20-30 cm) and the spatial distribution of soil AP in the tillage layer (0-20 cm). Furthermore, the correlation between pH and AP was analyzed. The results showed that mean pH values of typical yellow-cinnamon and typical fluvo-aquic soils from three soil layers were 4.98, 4.93, 5.31, and 5.46, 5.81, 6.26, respectively, which gradually increased with soil depths. However, there was no significant difference among the three soil layers. Mean pH values of typical lime concretion black soil from the three soil layers were 5.23, 5.43 and 6.03, respectively, and that of the 20-30 cm soil layer was significantly higher than that of the 0-10 cm (by 0.8-1 pH unit) and the 10-20 cm layers. The pH of the 20-30 cm soil layer of the calcareous lime concretion black and moist soils were also significantly higher than that of the 0-10 and 10-20 cm soil layers. The AP contents of the typical yellow-cinnamon, typical lime concretion black, moist, typical fluvo-aquic and calcareous lime concretion black soils in 0-20 cm soil layer were 8.85-54.75, 4.27-37.49, 8.22-51.80, 6.07-34.82, and 13.22-22.85 mg·kg-1, respectively. The results of the map indicated that the areas with low AP were distributed in the middle of the study area in blocks, and the areas with high AP were distributed around the study area in dots and flakes. The pH values of the typical yellow-cinnamon, typical lime concretion black, and moist soils positively correlated with the content of AP in the 0-20 cm soil layer. In conclusion, the heavy clay soil in southern Henan Province became stratified acidification, which slowed down along the soil depth. Soil AP contents in the tillage layer were distributed unevenly in the study area, and were affected by soil types and soil pH. These results would be useful for the improvement of heavy clay soil acidification in the southern part of the North China Plain.
Subject(s)
Soil Pollutants , Soil , China , Clay , Hydrogen-Ion Concentration , Phosphorus/analysis , Soil/chemistry , Soil Pollutants/analysisABSTRACT
The potato cyst nematode Globodera pallida is a globally regulated potato pest. It was detected for the first time in the United States in the state of Idaho in 2006, and as of February 2019, the infestation is limited to 1,326 hectares. G. pallida is a specialized obligate sedentary endoparasite that can survive in the soil for up to 30 years in the absence of its potato host. In highly infested fields, the nematode can reduce tuber yields up to 80% and is spread mainly through the movement of soil, tubers, or farm equipment. The objectives of this study were to describe the spatiotemporal pattern of G. pallida in infested fields and model its dispersal patterns in southeastern Idaho. We used geostatistical tools and simulation models for precise mapping and to describe the relationships between G. pallida incidence and the spatial configurations. We found that the nematode is spatially clustered and prevalent around edges of fields, and its dispersal pattern followed the direction of cultivation. We found that the absence of potato in an infested field significantly reduced the number of cysts sampled each year subsequent to the initial delimitation sampling in 2007. Phytosanitary measures prohibiting the growth of potato contributed to stopping nematode reproduction, and the use of chemical fumigants and biofumigant cover crops contributed to a significant reduction in egg viability. We observed a process of a nonlinear decline in the prevalence of cysts as the distance separation from the primary infestation focus increased. A power law model was used to fit G. pallida dispersal capabilities. This study contributed to describing G. pallida infestation for Idaho. The goal of this study is to provide information on the spatial pattern and landscape ecology of G. pallida in Idaho for policy makers, industry, and researchers as well as facilitate common understandings on the challenges and opportunities for controlling this pest in Idaho.
Subject(s)
Solanum tuberosum , Tylenchoidea , Animals , Idaho , Plant Diseases , Spatio-Temporal AnalysisABSTRACT
Ornamental trees bring benefits for human health, including reducing urban pollution. However, some species, such as plane trees (Platanus sp.), produce allergenic pollen. Consequently, urban maps are a valuable tool for allergic patients and allergists, but they often fail to include variables that contribute to the "building downwash effect", such as the width and shape of streets and the height of buildings. Other factors that directly influence pollen dispersion (slopes and other geographical features) also have not traditionally been discussed. The LiDAR (Laser Imaging Detection and Ranging) technique enables one to consider these variables with high accuracy. This work proposes an Aerobiological Index to create Risk maps for Ornamental Trees (AIROT) and the establishment of potential areas of risk of exposure to Platanus pollen. LiDAR data from five urban areas were used to create the DEM and DSM (Digital Elevation and Surface Models) needed to perform further analysis. GIS software was used to map the points for each city and to create risk maps by Kriging, with stable (3 cases) and exponential function (2 cases) as the optimal models. In short, the AIROT index was a useful tool to map possible biological risks in cities. Since AIROT allows each city to consider its own characteristics, including geographical specifications, by using remote sensing and geostatistics techniques, the establishment of risk maps and healthy itineraries is valuable for allergic patients, allergists, architects and urban planners. This new aerobiological index provides a new decision-making tool related to urban planning and allergenicity assessment.
Subject(s)
Environmental Monitoring/methods , Hypersensitivity/epidemiology , Air Microbiology , Allergens , Cities , Humans , Pollen , Risk Assessment/methods , Spatial Analysis , TreesABSTRACT
Daily fluctuations of the airborne pollen concentrations produce variations on symptomatology in allergic population. Such fluctuations are influenced by local vegetal coverage, flowering phenology, geography and climatology. Since 1991, airborne pollen of Malaga province (southern Spain) has been monitored in 7 different locations. Malaga station has been kept operational uninterruptedly throughout the studied period, while the rest of the stations only worked in periods of 2-4 years. Weekly, its pollen information is updated online to inform the population in order to prevent allergic diseases. Increasing the spatial resolution of pollen information would be very useful for allergic population living at unsampled locations. Due to the impossibility of keeping operational a high number of pollen stations covering the whole province of Malaga, the aim of this study is to create spatial models to extrapolate and forecast the pollen concentrations to Malaga province by using the concentrations registered at the capital as unique input. To do so, the relationships obtained between the airborne pollen concentrations detected at Malaga city and those detected at the other stations have been used to elaborate models for the main pollen types registered at the province. These models were spatially interpolated all over the province by using co-kriging techniques and the Compensated Thermicity Index as covariable. As result of this work, pollen distribution of the 8 most prevalent taxa has been depicted all over the whole Malaga province and an allergy alert system has been set up to extrapolate pollen information from Malaga to the whole province.
Subject(s)
Air Pollutants/analysis , Air Pollution/statistics & numerical data , Allergens/analysis , Environmental Monitoring/methods , Pollen/chemistry , Seasons , Forecasting , Humans , Spain , Spatio-Temporal AnalysisABSTRACT
Achieving better monitoring and radiation risk assessment is among the main issues in environmental studies. In this regard, natural radioactivity measurements in sediments can provide useful information about the environmental transport mechanism and about the sources of radionuclides. Anzali wetland, as the study area of this research, is located on the southwestern shore of the Caspian Sea with rapidly changing ecosystems. Because of its strategic location, increasing pollution levels, decreasing water table, and increasing sediment discharge from rivers, Anzali wetland has a unique significance in terms of studying its radioactivity from sediment and soil samples. The average 226Ra, 235U, 232Th, 137Cs, and 40K values for 33 sediment and soil samples were 24.66, 3.72, 31.94, 11.66, and 506.38 Bq kg-1, respectively. Variography analyses revealed a spatial structure with minimum/maximum variance equal to 3/8 from 135°/45° azimuth direction. In addition, the fractal geometry indicates values higher than 3.7, 24.5, 30, 25, and 475 Bq kg-1 as anomalous values for 235U, 226Ra, 232Th, 137Cs, and 40K using Kriging estimated data with a search radius of 5000 m, respectively. Compared with the average values published by UNSCEAR (2008) for earth's crust average and compared with the values for the southern areas of Iran (Oman Sea), the estimated average and anomalous data for a pollutant at Anzali wetland do not exceed the reference data. The higher values in the samples of this study could be related to specific environmental problems such as industrial wastewater from about 30 polluted factories transported by 10 major rivers. Agricultural wastes, such as herbicides, pesticides, and fertilizers from rice fields, and being a tourist attraction zone at sea beach are the other most possible pollution sources in the study area.
Subject(s)
Cesium Radioisotopes/analysis , Geologic Sediments/chemistry , Potassium Radioisotopes/analysis , Radiation Monitoring/methods , Radium/analysis , Soil Pollutants, Radioactive/analysis , Thorium/analysis , Uranium/analysis , Iran , Oman , Rivers/chemistry , Wastewater/chemistry , WetlandsABSTRACT
In this study, an innovative approach that combines Principal Component Analysis (PCA) and Gaussian process regression (Kriging method), never used before in the assessment of human exposure to electromagnetic fields (EMF), was applied to build space-dependent surrogate models of the 3D spatial distribution of the electric field induced in central nervous system (CNS) of children of different ages exposed to uniform magnetic field at 50 Hz of 200 µT of amplitude with uncertain orientation. The 3D surrogate models showed very low normalized percentage mean square error (MSE) values, always lower than 0.16%, confirming the feasibility and accuracy of the approach in estimating the 3D spatial distribution of E with a low number of components. Results showed that the electric field values induced in CNS tissues of children were within the ICNIRP basic restrictions for general public, with 99th percentiles of the E values obtained for each orientation showing median values in the range 1.9-2.1 mV/m. Similar 3D spatial distributions of the electric fields were found to be induced in CNS tissues of children of different ages. Bioelectromagnetics. 9999:1-10, 2018. © 2019 Bioelectromagnetics Society.
Subject(s)
Environmental Exposure/analysis , Magnetic Fields/adverse effects , Models, Anatomic , Adolescent , Child , Environmental Exposure/adverse effects , Female , Humans , Male , Normal Distribution , Principal Component Analysis , Stochastic ProcessesABSTRACT
Information about the soil quality of different land-use types and topographies is essential for the sustainable development, utilization, and protection of soil resource in coastal areas. In this study, representative topsoil samples were collected from Liandao Island, China, and soil water content (SWC), soil bulk density (BD), total nitrogen (TN), soil organic matter (SOM), ammonium nitrogen (NH4+-N), nitrate nitrogen (NO3--N), available phosphorus (AP), available potassium (AK), soil salt content (SSC), and pH were recorded. The suitable minimum soil data set (MDS) was computed by principal component analysis (PCA) and the soil quality index (SQI) was then determined. The spatial distribution of the SQI was analyzed using ordinary kriging interpolation. The effects of topographical parameters (digital elevation model [DEM], slope, and aspect) and land-use types (vegetation [V], water resource conservancy land [WRC], sandy land [SL], unused land [UL], and built-up land [BL]) on SQI were then analyzed in detail. The parameters included in the MDS were TN, pH, and BD, which together accounted for 84.371% of the variation in soil quality. The SQI varied from 0.189 to 0.772 in the study area. The correlation coefficients between SQI and DEM, slope, and aspect were 0.498, 0.294, and 0.137, respectively (p < 0.01). The highest SQI score was found at an elevation of 110 m, with a slope of 68.2° and an aspect of 246.6, in the vegetation land-use type. Soil quality differed significantly (p = 0.0000) among the land-use types, with the following ranking: V > UL > SL > BL. Our results provide land managers with an important reference for the development, utilization, and protection of soil resource in coastal zones such as Liandao Island, China.
Subject(s)
Environmental Monitoring/methods , Soil/chemistry , China , Islands , Nitrogen/analysis , Phosphorus/analysis , Potassium , Spatial AnalysisABSTRACT
Modeling of hydrothermal carbonization (HTC) of poultry litter to high-value materials was conducted in order to understand the process and predict the influence of process parameters on product properties. Reaction temperature and time were considered as inputs, whereas carbon and inorganic phosphorous recovery were considered as responses in the model. Artificial neural network (ANN) model was used in order to correlate the process parameters to the outputs. The model was trained and validated using the data collected from HTC experiments carried out at temperatures between 150â¯≤â¯Tâ¯≤â¯300⯰C, and residence time between 30â¯≤â¯tâ¯≤â¯480â¯min. In order to improve the predictability of ANN, more theoretical data points were generated using Kriging approach based on the available measured data. Kriging interpolation improved the ANN model dramatically in training and validation phases, where the carbon recovery model fitting was improved by 0.94% and 9.2% in training and validation respectively, and the inorganic phosphorous (IP) recovery model fitting was improved by a staggering 16.4% and 19.6% in training and validation respectively. This improvement is also reflecting on the derived profiles of carbon and IP recovery in terms of the process parameters. The validated model was then used to understand the effect of process parameters on the response. It was revealed that temperature has more significant effect on the carbon and phosphorous recovery, while the effect of reaction time is more important at low reaction temperatures. The derived profiles shows a monotonic increase in IP recovery and a monotonic decrease in Carbon recovery at higher temperatures and time, this is due to multiple mechanism occurring simultaneously in the HTC reactor at various temperatures and times.
Subject(s)
Carbon , Phosphorus , Animals , Hot Temperature , Poultry , TemperatureABSTRACT
Based on a grid (25 m X 25 m) equidistant sampling, the spatial variability of pH, organic matter, total nitrogen, available phosphorus, CEC and three typical heavy metal elements Cd, As and Pb in soil tillage layer (0-20 cm) were analyzed by using GIS and Geostatistics in the paddy field of 3.56 hm2 in Beishan Town, Changsha County, Hunan Province. The results showed that soil pH value and Pb content showed weak variation, and other indexes showed moderate variation. The order of variation was following available phosphorus ï¼ Cd ï¼ total nitrogen ï¼ organic matter ï¼ CEC ï¼ As ï¼ Pb ï¼ pH. Results of the semi-variance test showed that the best fitting model of the semi-variance function of organic matter, available phosphorus and As was exponential, and the best semi-variance function of pH, total nitrogen, CEC, Cd, Pb was spherical. All the indicators had a strong spatial correlation except for CEC, which showed moderate spatial correlation. Kriging interpolation analysis showed that pH, total nitrogen, CEC, Pb were plaque distribution, while organic matter, available phosphorus, Cd and As were block and banded distribution. Vegetation, topography and human activities were the main factors driving the variation of soil nutrients and heavy metals in the study area. The correlation between soil nutrients and heavy metals content was significant, among which pH and organic matter, Cd and Pb reached a very significant correlation level.
Subject(s)
Environmental Monitoring , Geographic Information Systems , Metals, Heavy/analysis , Oryza , China , Phosphorus , Soil , Soil PollutantsABSTRACT
The potato cyst nematode Globodera pallida is a globally regulated and quarantine potato pest. It was detected for the first time in the United States in the state of Idaho in 2006. A spatial analysis was performed to (i) understand the spatial arrangement of fields infested with G. pallida in southern Idaho using spatial point pattern analysis, and (ii) evaluate the potential threat of G. pallida for entry to new areas using spatial interpolation techniques. Data point locations, cyst numbers and egg viability values for each infested field were collected by USDA-APHIS during 2006 to 2014. Results showed the presence of spatially clustered fields infested with G. pallida (P = 0.003). We determined that the spread of G. pallida grew in diameter from the original center of infestation toward the southwest as an ellipsoidal-shaped cluster. Based on the aggregated spatial pattern of distribution, we determined that G. pallida spread followed a contagion effect scenario, where nearby infested fields contributed to the infestation of new fields, probably through soil contaminated agricultural equipment or tubers. We determined that the presence of G. pallida in southern Idaho is unlikely to be associated with new introductions from outside the state of Idaho. The aggregation pattern of fields infested with G. pallida, with an average of 4,263 cysts/ha and egg viability of 25%, facilitates quarantine activities and confines the propagation of this pest to a small area, which in 2017 was estimated to be 1,233 ha. The tools and methods provided in this study facilitate comprehensive approaches to improve G. pallida control and eradication programs as well as to raise public awareness of the problems surrounding this economically important potato pest.
Subject(s)
Plant Diseases/parasitology , Solanum tuberosum/parasitology , Tylenchoidea/physiology , Algorithms , Animals , IdahoABSTRACT
Soil phosphorus is an important indicator to measure the soil fertility, because the content of soil phosphorus has an important effect on physical and chemical properties of soil, plant growth, and microbial activity in soil. In this study, the soil samples collecting and indoor analysis were conducted in Zhoukou City located in the flooded area of the Yellow River. By using GIS combined with geo-statistics, we tried to analyze the spatial variability and content distribution of soil total phosphorus (TP) and soil available phosphorus (AP) in the study area. Results showed that TP and AP of both soil layers (0-20 cm and 20-40 cm) were rich, and the contents of TP and AP in surface layer (0-20 cm) were higher than in the second layer (20-40 cm). TP and AP of both soil layers exhibited variation at medium level, and AP had varied much higher than TP. TP of both layers showed medium degree of anisotropy which could be well modeled by the Gaussian model. TP in the surface layer showed strong spatial correlation, but that of the second layer had medium spatial correlation. AP of both layers had a weaker scope in anisotropy which could be simulated by linear model, and both soil layers showed weaker spatial correlations. TP of both soil layers showed a slowly rising change from southwest to northeast of the study area, while it gradually declined from northwest to southeast. AP in soil surface layer exhibited an increase tendency firstly and then decrease from southwest to the northeast, while it decreased firstly and then increased from southeast to the northwest. AP in the second soil layer had an opposite change in the southwest to the northeast, while it showed continuously increasing tendency from northwest to the southeast. The contents of TP and AP in the surface layer presented high grades and the second layer of TP belonged to medium grade, but the second layer of AP was in a lower grade. The artificial factors such as land use type, cropping system, irrigation and fertilization were the main factors influencing the distribution and spatial variation of soil phosphorus in this area.
Subject(s)
Phosphorus/analysis , Soil/chemistry , China , Floods , Geographic Information Systems , Rivers , Spatial AnalysisABSTRACT
Vegetation types restrict soil structure and heterogeneous processes of elements, which result in difference in spatial distribution of soil nutrients. In this study, the differences in contents of soil nutrients, TN, TP, TK, and soil organic matter (SOM) among different vegetation types were analyzed, and the accuracy of ordinary kriging, regression model and regression model based on vegetation type in predicting soil nutrients was compared. The results showed that, TN, TK and SOM were significantly (P<0.05) correlated to vegetation type, and TP had no significant correlation with vegetation type (P=0.390). TN and SOM had significant difference between shrubbery and arable land. TK had significant difference between arbor and scrub-grassland, shrubbery and arable land, and scrub-grassland and arable land, respectively. In a non-continuous typical small karst catchment, because of high spatial heterogeneity of terrain, the accuracy of multivariate linear regression model based on the real terrain factors of various points was considerably higher than that of ordinary kriging prediction method considering the locations of the known points and prediction points. Moreover, the regression model based on vegetation type improved the prediction accuracy of the TN.
Subject(s)
Soil/chemistry , Spatial Analysis , China , Nitrogen/analysis , Phosphorus/analysis , Plants , Potassium/analysisABSTRACT
In recent years, lanthanum modified bentonite has been increasingly applied to eutrophic lakes with the aim of converting potentially bio-available forms of phosphorus in sediments into biologically unavailable forms. In many of these applications, however, no attempts have been made to assess the efficiency and efficacy of the measure in terms of its effect on the sediment. In this study, we collected sediment cores from a heavily eutrophied lake that has previously been treated with lanthanum modified clay. This restoration method is based on the strong ionic bond formed between lanthanum and phosphate which results in the formation of LaPO4 (Rhabdophane) in the sediment. In order to determine the changes that had occurred in the sediments as a result of the addition of the clay, we measured the vertical distribution of lanthanum in the collected cores, calculated La:P ratios of the different sediment layers and used the ratios to determine whether or not the applied dosage was sufficient. By means of the geostatistical method of kriging these values were transferred into maps of different depth intervals to visualize the results. The results indicate that the La:P ratio may be a useful tool which allows lake managers to measure the vertical distribution of lanthanum in sediments following treatments and determine whether or not dosages are sufficient to permanently render sediment phosphorus biologically unavailable. The method may also provide a basis on which to decide whether or not smaller reapplications are needed and can be used to control the dispersion of the material.