Formation and In Vitro Simulated Digestion Study of Gelatinized Korean Pine Seed Oil Encapsulated with Calcified Wax.

Natural waxes have demonstrated exceptional potential as oil gels for saturated and trans fatty acids, but their application has been limited by issues such as temperature sensitivity, lack of stability and durability, and compatibility. In this study, three types of wax (Beeswax (BW), Rice bran wax (RBW), and Carnauba wax (CW)) were combined with calcium hydroxide to produce calcified wax. The calcified Korean pine seed oil gel obtained by heating and stirring with Korean pine seed oil is responsive to temperature and has environmental adaptability. The effects of critical gel concentration, temperature regulation, texture properties, microstructure, oil-holding capacity, and FT-IR on the quality parameters of oil gel were investigated. Additionally, an in vitro digestion model was developed to comprehend the decomposition rate of fat during gel structure digestion and transportation. The results demonstrated a close correlation between the critical gelation concentration and calcium ion content. Furthermore, after calcification, the hardness followed the order BW > CW > RBW. Moreover, there was an approximate 10 °C increase in wax melting point. Conversely, BW:Ca exhibited the lowest oil leakage. The microstructures revealed that the oil gels formed post-wax calcification exhibited similar fractal dimension (Db) values (<7 µm), and the intermolecular forces were characterized by van der Waals forces, which were consistent with those observed in the non-calcified group. In conjunction with the vitro digestion simulation, our findings demonstrated that RBW and CW oil gels gradually released 20%, 35%, and 35% of free fatty acids (FFA) within the initial 30 min of intestinal digestion. Importantly, the FFA release rate was significantly attenuated, thereby providing a foundation for developing wax-based gel processed foods that facilitate gentle energy release benefits for healthy weight management.

Spent coffee grounds as supporting materials to produce bio-composite PCM with natural waxes.

Novel kinds of bio composite Phase change materials were prepared by the use of bio-wastes. Of the by-products, coffee wastes, which is currently consumed and abandoned as coffee as a drink, was used as the supporting material for PCM. It was found through chemical composition of FTIR of SCBW, SCPW, SCGW and that the coffee wastes were effectively vacuum impregnated into each natural wax. As a result of TGA, the thermal stability of SCBW, SCPW, SCGW and SCNW was checked. In addition, the DSC results were used to determine the heat storage performance of each material. Micro-morphological analysis with FE-SEM showed whether the impregnation was successful. The use of bio-compatible PCM by-products is economical as well as environmentally friendly and is sufficient for building applications in terms of thermal performance compared to other bio-composites.