Valorization of poultry slaughterhouse sludge oil: a strategy to reduce Brazil's dependency on soybean oil in the biodiesel industry.

During the poultry industrialization process the so-called sludge oil, a residual chicken fat, is recovered in the wastewater treatment plant and its use presents potential as raw material for biodiesel production. Thus, the aim of the study was to prepare blends of sludge oil with soybean oil to obtain fatty acid methyl esters (FAME) through the homogeneous alkaline transesterification reaction. To perform this study, a simple pre-treatment process - heating and subsequent filtration - was used, allowing sludge oil to be mixed with soybean oil to compose blends, without the need to use more sophisticated pre-treatment processes. After this step, blends ranging from 5% to 90% (m/m) of sludge oil mixed with soybean oil were prepared. The results showed that the molar ratio (1:6 oil blend:methanol), catalyst concentration 0.5% NaOH (mcat/moil), at 65 °C for 60 min yielded FAME above 99.0 and 90.0% (m/m) for blends with up to 5 and 15% sludge oil, respectively. By increasing the temperature to 70 °C, under the same selected parameters, the blend with 10% sludge oil provided yield above 99.0% (m/m), presenting appropriate physicochemical properties, within the parameters required by National Agency of Petroleum, Natural Gas and Biofuels (ANP). These findings show the great potential sludge oil provides to reduce Brazil's dependency on soybean oil for biodiesel production.Highlights Sludge oil, a waste raw material for biodiesel production, is not yet explored in Brazil.A procedure for biodiesel production using soybean oil and sludge oil blends was proposed.The best reaction condition was 1:6 oil blend:MeOH molar ratio; 0.5% NaOH (mcat/moil), at 70 °C for 60 min.Biodiesel yield was higher than 99% (m/m) under optimal reaction conditions.Sludge oil represents a promising waste raw material for biodiesel production.

Catalytic efficiency of the eggshell calcined and enriched with glycerin in the synthesis of biodiesel from frying residual oil.

Currently, there are several studies using calcium oxide, calcium alkoxide, and calcium hydroxide for biodiesel production. However, there is still a lack of studies highlighting the use of calcium diglyceroxide (calcium oxide enriched with glycerin in the presence of methanol) as a catalyst in the transesterification process. Therefore, the present work aimed to investigate the catalytic efficiency and reutilization of the eggshell calcined and enriched with glycerin and methanol (ECEG), in the synthesis of methylic esters from frying residual oil. As a result, thermochemically modified eggshells showed catalytic efficiency during methylic transesterification of residual oils in mass concentrations of 15%, 5%, 3%, and 1% due to the presence of a high level of esters (97.39, 96.97, 97.75, and 92.96%, respectively). The initial concentration of the enriched eggshell used in methanolysis had a direct effect on the final ester mixture. A 15% increase in the water content of the frying oil contributed to an increase in the ester content. The ECEG was reactive and efficient for four reaction cycles (without reactivation of the catalytic sites) due to the evidence of a high ester content (97.85%, 98.67%, 98.89%, 98.46%), reaching the standard quality of worldwide biodiesel regulations. Graphical abstract.